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Nickel(II) complexes of a thiosemicarbazone prepared from 2-Acetylpyridine

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Summary

The ligand 3-azabicyclo[3.2.2]nonane-3-thiocarboxylic acid 2-[1-(2-pyridinyl)ethylidene]hydrazide (HL), which is observed in an unusual tautomeric form in the solid state, and its selenium analogue (HLSe) have been used to prepare a series of nickel(II) complexes. Compounds of the general formula [NiLX] (X=Cl, Br, NCS, N3, NO2 or NCSe) as well as [Ni(LSe)Cl] have been found to be diamagnetic, planar complexes. A single crystal study of [NiL(NCS)] shows the deprotonated ligand bound in a tridentate mannervia its pyridyl nitrogen, imine nitrogen and the thione sulphur atom with the nitrogen atom of the thiocyanato-ligand occupying the fourth coordination position. The solids prepared from the nickel(II) salts having tetrafluoroborate, nitrate and iodide ions approximate to octahedral symmetry and have neutral HL ligands coordinated in a bidentate fashionvia the pyridine and imine nitrogens with the remaining coordination sites being occupied by the anions or water molecules. The [NiL2] solid is also octahedral with the two deprotonated ligands bonding as tridentate groupsvia the same atoms as in the [NiLX] complexes.

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Author notes

  1. Alfonso Bavoso

    Present address: Departimento di Chimica, Universita di Napoli, via Mezzocannone 4, 80134, Naples, Italy

Authors and Affiliations

  1. Department of Chemistry, Illinois State University, 61761, Normal, IL, USA

    Douglas X. West

  2. Division of Experimental Therapeutics, Walter Reed Army Institute of Research, 20307, Washington, DC

    John P. Scovill

  3. Laboratory of Chemistry, National Heart, Lung, and Blood Institute, National Institutes of Health, 20892, Bethesda, MD

    J. V. Silverton & Alfonso Bavoso

Authors
  1. Douglas X. West
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  2. John P. Scovill
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  3. J. V. Silverton
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  4. Alfonso Bavoso
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West, D.X., Scovill, J.P., Silverton, J.V. et al. Nickel(II) complexes of a thiosemicarbazone prepared from 2-Acetylpyridine. Transition Met Chem 11, 123–131 (1986). https://doi.org/10.1007/BF00637013

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