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Multinuclear NMR Spectroscopic Characterization of Vanadium(V) Alkylperoxo Complexes VO(OOtBu)k(OnBu)3-k, where k = 1, 2, 3

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Abstract

Using 51V, 17O, 13C and 1H NMR spectroscopy, vanadium(V) alkylperoxo complexes VO(OOtBu)k(OnBu)3-k, where k = 1, 2 and 3, were characterized in the reaction of VO(OnBu)3 with tBuOOH in CH2Cl2.

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Authors and Affiliations

  1. Boreskov Institute of Catalysis, Pr. Ak. Lavrentieva 5, Novosibirsk, 630090, Russia

    D.E. Babushkin & E.P. Talsi

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  1. D.E. Babushkin
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  2. E.P. Talsi
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Babushkin, D., Talsi, E. Multinuclear NMR Spectroscopic Characterization of Vanadium(V) Alkylperoxo Complexes VO(OOtBu)k(OnBu)3-k, where k = 1, 2, 3. Reaction Kinetics and Catalysis Letters 71, 115–120 (2000). https://doi.org/10.1023/A:1010394401961

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