Abstract
Under steady state conditions also La2O3 and ThO2, both having strong ionic character, unfilled d- and f-orbitals and a large metal ion radius proved to be order(s) of magnitude more active than oxides of s, sp and d-metals.
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Mink, G. Steady state activity of acidic, basic and amphoteric oxides in the CO2+CS2=2COS reaction. React Kinet Catal Lett 68, 221–227 (1999). https://doi.org/10.1007/BF02475505
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DOI: https://doi.org/10.1007/BF02475505