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Steam reforming of methanol over Cu/ZrO2. Role of ZrO2 support

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Abstract

Cu/ZrO2 was highly active and selective for the title reaction. The activity obtained exceeded greatly that obtained over Cu/SiO2. It was shown that the precursors highly dispersed on zirconia support were readily reduced to very fine particles of metallic copper.

Abstract

Катализатор Cu/ZrO2 оказался сильно активным и селективным в заглавной реакции. Полученная активность почти достигает активности на Cu/SiO2. Найдено, что прекурзоры, сильно диспергированные на циркониевом носителе, легко восстанавливаются до очень тонких частиц металлической меди.

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Authors and Affiliations

  1. Department of Chemical Process Engineering, Hokkaido University, 060, Sapporo, Japan

    N. Takezawa, M. Shimokawabe, H. Hiramatsu, H. Sugiura & T. Asakawa

  2. Muroran Institute of Technology, 050, Muroran, Japan

    H. Kobayashi

Authors
  1. N. Takezawa
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  2. M. Shimokawabe
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  3. H. Hiramatsu
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  4. H. Sugiura
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  5. T. Asakawa
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  6. H. Kobayashi
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Takezawa, N., Shimokawabe, M., Hiramatsu, H. et al. Steam reforming of methanol over Cu/ZrO2. Role of ZrO2 support. React Kinet Catal Lett 33, 191–196 (1987). https://doi.org/10.1007/BF02066722

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  • DOI: https://doi.org/10.1007/BF02066722

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