Abstract
Surface reduction of complex Mo-containing oxide catalysts by the initial reactant in propene ammoxidation increases its activity in isomerization of butene-1 to butene-2. Isomerization and conversion of ammonia, propene and their mixtures are suggested to take place on the same active centers of the catalyst.
Abstract
Восстановление човерхности сложного Mo-содержащего оксидного катализатора исходными компонентами реакции окислительного аммонолиза пропилена приводит к повышению его активности в реакции изомеризации гутена-1 в бутени-2. Сделан вывод, что реаксия изомеризации и превращения аммиака, пропилена и их смеси осуществляются на одних и тех же активных центрах катализатора.
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Gadzhiev, K.N., Khanmamedova, A.K., Adzhamov, K.Y. et al. Influence of initial reactants in propene ammoxidation on the isomerization activity of complex Mo-containing oxide catalysts. React Kinet Catal Lett 29, 403–407 (1985). https://doi.org/10.1007/BF02068533
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DOI: https://doi.org/10.1007/BF02068533