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Changes in the catalytic properties of a multicomponent molybdenum catalyst under vibro-fluidized catalyst bed conditions

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Abstract

Activation effect of oxidative dehydrogenation of butene-l on a multicomponent molybdenum catalyst at various temperatures has been studied by pulse and flow techniques. It is shown that under vibrofluidization not only reactive but also adsorption properties of the catalyst surface change. Oxygen consumption in the reaction process has been examined.

Abstract

Импуьсным и проточным методом при различных температурах исследован эффект активации реакции окислительного дегидрирования бутена-1 на примере многокомпонентного молибденового катализатора. Показано, что в условиях виброожижения меняются не только реакционные, но и адсорбционные свйства поверхности. Рассмотрено потребление кислрода в ходе реакции.

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Authors and Affiliations

  1. Institute of Catalysis, 630090, Novosibirsk, USSR

    A. V. Simakov, S. A. Veniaminov, N. N. Sazonova & G. B. Barannik

  2. Zentralinstitut für Physikalische Chemie, AdW der DDR, 1199, Berlin, DDR

    W. Walkov & K. -H. Schnabel

Authors
  1. A. V. Simakov
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  2. S. A. Veniaminov
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  3. W. Walkov
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  4. N. N. Sazonova
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  5. G. B. Barannik
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  6. K. -H. Schnabel
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Simakov, A.V., Veniaminov, S.A., Walkov, W. et al. Changes in the catalytic properties of a multicomponent molybdenum catalyst under vibro-fluidized catalyst bed conditions. React Kinet Catal Lett 29, 363–369 (1985). https://doi.org/10.1007/BF02068528

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  • DOI: https://doi.org/10.1007/BF02068528

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