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Kinetics and mechanism of the oxidation of bis(acetylacetonato)-cobalt(II) by cumene hydroperoxide in the presence of pyridine

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Abstract

Stoichiometric reaction of bis(acetylacetonato) cobalt(II) with cumene hydroperoxide in chloroform solutions containing added pyridine has been studied by the PMR method.

Abstract

Методом ПМР изучена стехиометрическая реакция между бис (ацетилацетонатом) Co(II) и гидроперекисью кумола в растворах хлороформа, содержащих добавки пиридина.

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Authors and Affiliations

  1. Institute of Catalysis, 630090, Novosibirsk, USSR

    Yu. S. Zimin, E. P. Talzi, V. M. Nekipelov, V. D. Chinakov & K. I. Zamaraev

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  1. Yu. S. Zimin
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  2. E. P. Talzi
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  3. V. M. Nekipelov
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  4. V. D. Chinakov
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  5. K. I. Zamaraev
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Zimin, Y.S., Talzi, E.P., Nekipelov, V.M. et al. Kinetics and mechanism of the oxidation of bis(acetylacetonato)-cobalt(II) by cumene hydroperoxide in the presence of pyridine. React Kinet Catal Lett 29, 225–233 (1985). https://doi.org/10.1007/BF02067972

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  • DOI: https://doi.org/10.1007/BF02067972

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