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Catalytic properties of Cu(Acac)2 anchored to shock-compressed MgO and MgF2 supports

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Abstract

Catalytic properties of Cu(Acac)2 anchored to shock-compressed MgO and MgF2 in model reactions of hydrogenation and isomerization of heptene-1 have been studied. It is shown that by changing the defect structure of the support via shock treatment at various temperatures, the activity and selectivity of metal complex catalysts can be affected.

Abstract

Изучены каталитические свойства цетилацетоната меди Cu(Acac)2, закрепленного на MgO и MgF2 в модельных реакциях гидрирования и изомеризации гептена-1. Показано, что изменение дефектной структуры носителя, достигаемое путем воздействияна него импульсным давлением при разных температурах, влияет на активность и селективность закрепленных металлокомплексных катализаторов.

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Bokarev, V.P., Bondarev, Y.M., Temnitskii, I.N. et al. Catalytic properties of Cu(Acac)2 anchored to shock-compressed MgO and MgF2 supports. React Kinet Catal Lett 27, 181–184 (1985). https://doi.org/10.1007/BF02064483

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  • DOI: https://doi.org/10.1007/BF02064483

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