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Chlorination of V2O5 by CCl4. The proposed reaction mechanism

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Abstract

Initial stage of the reaction of CCl4 with V2O5 has been studied by MS and XPS techniques. According to the proposed mechanism dissociatively chemisorbed CCl4 transforms to CO2 via adsorbed COCl2, while surface vanadium atoms involved are gaining step by step two chlorine atoms before the formation of the volatile end-product VOCl3.

Abstract

Первоначальная стадия реакции CCl4 с V2O5 была изучена с помощью массспектрометрии и рентгеновской фотоэлектронной спектроскопии. По предложенному механизму диссоциативно-хемосорбированный CCl4 превращается в CO2 через COCl2, поверхностные атомы ванадия постепенно принимают два хлора перед образованием летучего конечного продукта реакции VOCl3.

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References

  1. I.Z. Babievskava, I. Bertóti, G. Mink: Acta Chim. Acad. Sci. Hung. (to be published)

  2. G. Mink, B. Pődör, I. Bertóti: Travaux ICSOBA,12, 239 (1982).

    Google Scholar 

  3. G. Mink, I. Bertóti, T. Székely: React. Kinet. Catal. Lett.,27, 33 (1985)

    Google Scholar 

  4. R. Larsson, B. Folkesson, G. Schön: Chem. Scr.,3, 88 (1973).

    Google Scholar 

  5. L. Fiermans, P. Claws, W. Lambrecht, L. Vandenbroucke, J. Vennik: Phys. Stat. Sol. (a),59, 485 (1980).

    Google Scholar 

  6. J. H. Scofeld: J. Electron Spectrosc. Relat. Phenom.,8, 129 (1976).

    Google Scholar 

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Authors and Affiliations

  1. Research Laboratory for Inorganic Chemistry of the Hungarian Academy of Sciences, Pf. 132, H-1502, Budapest, Hungary

    G. Mink, I. Bertóti & T. Székely

  2. Istituto di Teoria e Struttura Elettronica, CNR, Roma, Italy

    C. Battistoni

Authors
  1. G. Mink
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  2. I. Bertóti
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  3. C. Battistoni
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  4. T. Székely
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Mink, G., Bertóti, I., Battistoni, C. et al. Chlorination of V2O5 by CCl4. The proposed reaction mechanism. React Kinet Catal Lett 27, 39–45 (1985). https://doi.org/10.1007/BF02064457

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  • DOI: https://doi.org/10.1007/BF02064457

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