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Transmethylation of trimethylbenzenes and toluene on H- and Ni/H-mordenites

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Abstract

Under pressure in the presence of hydrogen the calculated transmethylation equilibrium composition was approached on synthetic H-mordenite at 350°C, on natural H-mordenites at 450–500°C. The high activity of H-mordenite is maintained without deactivation by using the reduced Ni, H-form of synthetic mordenite with a nickel content of 2.4 mass %.

Abstract

Под давлением в присутствии водорода достигается расчетный равновесный состав трансметилирования на синтетическом Н-мордените при 350°C и на природном Н-мордените при 450–500°C. Н-Морденит высокой активности удалось получить без дезактивации, ислользуя восстановленную Ni, Н-форму синтетического морденита с содержанием никеля 2,4 масс. %

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Szakács, S., Papp, J., Lejtovicz, D. et al. Transmethylation of trimethylbenzenes and toluene on H- and Ni/H-mordenites. React Kinet Catal Lett 21, 365–370 (1982). https://doi.org/10.1007/BF02070641

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  • DOI: https://doi.org/10.1007/BF02070641

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