Skip to main content
SpringerLink
Log in

Structure effects of palladium complexes with phosphinated polystyrene on their catalytic properties in phenylacetylene hydrogenation

  • Published:
Reaction Kinetics and Catalysis Letters Aims and scope Submit manuscript

Abstract

The structure of palladium acetate complexes with phosphinated polystyrene has been studied by IR and UV spectroscopy. The results indicate that on polystyrene both mono- and dinuclear palladium complexes are formed. The comparison of the catalytic properties of palladium complexes on phosphinated polystyrene with those of mono- and dinuclear complexes supported on silica confirmed the formation of dinuclear palladium complexes on polystyrene surface.

Abstract

Методами ИК-и УФ-спектроскопии исследовано строение комплексов ацетата паллалия с фосфинированным полистиролом. На основании полученных результатов сделан вывод, что на полистироле наряду с моноядерными комплексами образуются также и биядерные комплексы палладия. Сравнение каталитических свойств комплексов палладия на фосфинированном полистироле со свойствами моно- и биядерных комплексов, закреплённых на силикагеле, подтвердило предположение об образовании на поверхности полистирола биядерных комплексов палладия.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. C.U. Pittman, S.K. Wun, S.E. Jacobson: J. Catal.,44, 87 (1976).

    Article  Google Scholar 

  2. C. Carlini, G. Braca, F. Ciardelli, G. Sbrana: J. Mol. Catal.,2, 379 (1977).

    Article  Google Scholar 

  3. V.A. Semikolenov, V.A. Likholobov, P.A. Zhdan, A.P. Shepelin, Yu.I. Yermakov: Kinet. Katal., 21, 2, 429 (1980).

    Google Scholar 

  4. T.A. Stephenson, G. Wilkinson: J. Inorg. Nucl. Chem.,29 2122 (1967).

    Article  Google Scholar 

  5. N.M. Zhavoronkov, I.I. Moiseev: Koord. Khim.,4, 803 (1978).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Catalysis, Novosibirsk, USSR

    V. A. Semikolenov & V. A. Likholobov

  2. Instituto di Chimica Organica Industriale, Università di Pisa, Italia

    G. Valentini, G. Braca & F. Ciardelli

Authors
  1. V. A. Semikolenov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. V. A. Likholobov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. G. Valentini
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. G. Braca
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. F. Ciardelli
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Semikolenov, V.A., Likholobov, V.A., Valentini, G. et al. Structure effects of palladium complexes with phosphinated polystyrene on their catalytic properties in phenylacetylene hydrogenation. React Kinet Catal Lett 15, 383–388 (1980). https://doi.org/10.1007/BF02098720

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02098720

Keywords

Search

Navigation