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Study of the interaction of atomic oxygen and nitrogen with ruthenium by the bond interaction method

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Abstract

The heats of atomically adsorbed oxygen and nitrogen on Ru(0001) and Ru(1010) planes have been calculated by the semiempirical bond interaction method. The calculations show that oxygen is strongly adsorbed on ruthenium, while molecular nitrogen cannot be chemisorbed on ruthenium.

Abstract

Полуэмпирическим методом взаимодействующих связей рассчитаны теплоты атомарно-адсорбированных кислорода и азота на грани (000I) и (I0I0) рутения. На основании расчетов показано, что Ru должен обладать высокой адсорбционной способностью по отношению к кислороду, в то время как молекулярный азот на рутении не может хемосорбироваться.

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Authors and Affiliations

  1. Institute of Organic Catalysis and Electrochemistry, Alma-Ata, USSR

    K. Dosumov, N. N. Bulgakov, L. A. Sokolova & N. M. Popova

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  1. K. Dosumov
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  2. N. N. Bulgakov
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  3. L. A. Sokolova
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  4. N. M. Popova
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Dosumov, K., Bulgakov, N.N., Sokolova, L.A. et al. Study of the interaction of atomic oxygen and nitrogen with ruthenium by the bond interaction method. React Kinet Catal Lett 12, 435–439 (1979). https://doi.org/10.1007/BF02061750

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  • DOI: https://doi.org/10.1007/BF02061750

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