Abstract
Nuclear inelastic resonant scattering of synchrotron radiation was applied to the study solutions of 57Fe complexes. In order to reveal different inelastic contributions solutions of two different 57Fe complexes of different molecular dimensions with solvents of substantially different viscosities were studied. We argue that the only former experiment available in the literature overestimates the role of the diffusivity in affecting the spectrum. The first direct observation of an intramolecular vibrational transition assisting the nuclear resonance absorption in a liquid is reported.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
K. Burger, A. VÉrtes, Nature (London), 306 (1983) 353.
D. St. P. Bunbury, J. A. Elliott, H. E. Hall, J. M. Williams, Phys. Lett., 8 (1963) 34.
A. VÉrtes, D. L. Nagy, Mössbauer Spectroscopy of Frozen Solutions, Akadémiai Kiadó, Budapest, 1990.
E. Gerdau, U. Van BÜrck, R. RÜffer, Hyp. Int., 123/124 (1999) 3.
G. V. Smirnov, Hyp. Int., 123/124 (1999) 31.
M. Seto, Y. Yoda, S. Kikuta, X. W. Zhang, M. Ando, Phys. Rev. Lett., 74 (1995) 3828.
A. I. Chumakov, R. RÜffer, Hyp. Int., 113 (1998) 59.
A. I. Chumakov, W. Sturhahn, Hyp. Int., 123/124 (1999) 781.
X. Zhang, Y. Yoda, M. Seto, Y. Maeda, M. Ando, S. Kikuta, Japan J. Appl. Phys., 34 (1995) 330.
F. Sette, G. Ruocco, M. Kirsch, U. Bergmann, C. Masciovecchio, V. Mazzacurati, G. Signorelli, R. Verbeni, Phys. Rev. Lett., 75 (1995) 850.
A. I. Chumakov, A. Q. R. Baron, R. RÜffer, H. GrÜnsteudel, H. F. GrÜnsteudel, A. Meyer, Phys. Rev. Lett., 76 (1996) 4258.
K. S. Singwi, A. SjÖlander, Phys. Rev., 120 (1960) 1093.
H. Paulsen, H. Winkler, A. X. Trautwein, H. GrÜnsteudel, V. Rusanov, H. Toftlund, Phys. Rev., B 120 (1999) 975.
Y. Saito, J. Takemoto, B. Hutchinson, K. Nakamoto, Inorg. Chem., 11 (1972) 2003.
R. Haruki, S. Kitao, M. Seto, Yu. Maeda, T. Harami, X. W. Zhang, Y. Yoda, S. Kikuta, ICAME-99 poster T7/24.
A. VÉrtes, L. Korecz, K. Burger, Mössbauer Spectroscopy, Elsevier, Amsterdam, 1979, p. 296.
http://www-hasylab.desy.de/
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Vankó, G., Bottyán, L., Nagy, D.L. et al. Nuclear Inelastic Scattering of Synchrotron Radiation on Solutions of 57Fe Complexes. Journal of Radioanalytical and Nuclear Chemistry 246, 97–100 (2000). https://doi.org/10.1023/A:1006785115244
Issue Date:
DOI: https://doi.org/10.1023/A:1006785115244