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Characterization of Natural Chromite Samples from Ophiolite Complexes in the Philippines by 57Fe Mössbauer Spectroscopy

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Abstract

Mössbauer spectroscopy was applied to natural chromite samples from ophiolite complexes in the Philippines. Chemical and structural characterization of the chromite samples was also carried out using X-ray absorption fine structure (XAFS), X-ray diffraction (XRD) and X-ray fluorescence spectrometry (XRF). The Mössbauer spectra of the samples consisted of quadrupole doublets ascribable to Fe3+ in octahedral site, Fe3+ in tetrahedral site, and Fe2+ in tetrahedral site. The relative percentage of Fe3+ and Fe2+ ions suggested that these Philippine samples were formed under relatively high oxygen fugacity.

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Authors and Affiliations

  1. Graduate School of Arts and Sciences, The University of Tokyo, 3-8-1 Komaba, Meguro, Tokyo, 153-8902, Japan

    A. Kuno

  2. Graduate School of Arts and Sciences, The University of Tokyo, 3-8-1 Komaba, Meguro, Tokyo, 153-8902, Japan

    R. A. Santos, M. Matsuo & B. Takano

Authors
  1. A. Kuno
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  2. R. A. Santos
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  3. M. Matsuo
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  4. B. Takano
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Kuno, A., Santos, R.A., Matsuo, M. et al. Characterization of Natural Chromite Samples from Ophiolite Complexes in the Philippines by 57Fe Mössbauer Spectroscopy. Journal of Radioanalytical and Nuclear Chemistry 246, 79–83 (2000). https://doi.org/10.1023/A:1006724913427

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