Skip to main content
SpringerLink
Log in

Separation of lithium isotopes with the N3O2 trimerrifield peptide resin

  • Published:
Journal of Radioanalytical and Nuclear Chemistry Aims and scope Submit manuscript

Abstract

A study on the separation of lithium isotopes was carried out with 1,13-dioxa-4,7,10-triazacyclopentadecane-4,7,10-trimerrifield peptide resin [N3O23M]. The resin having N3O2 as an anchor group has a capacity of 0.2 meq/g dry resin. Upon column chromatography [0.1 cm (I.D)×30 cm (height)] using 1.0M NH4Cl solution as an eluent, a single separation factor of 1.00104 was obtained from the elution curve and isotope ratios based on theGlueckauf theory. The heavier isotope,7Li concentrated in the resin phase, while the lighter isotope,6Li enriched in the solution phase.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. E. A. Symons, Separ. Sci. Technol., 20 (1985) 633.

    CAS  Google Scholar 

  2. T. I. Taylor, H. C. Urey, J. Chem. Phys., 5 (1937) 597.

    Article  CAS  Google Scholar 

  3. E. Glueckauf, K. H. Baker, G. P. Kiit, Faraday Soc. Discuss., 7 (1949) 199.

    Google Scholar 

  4. B. E. Jepson, G. A. Carins, Report MLM-2622, 1979.

  5. K. Nishizawa, H. Watanabe, S. Ishino, M. Shinagawa, J. Nucl. Sci. Technol., 21 (1984) 133.

    CAS  Google Scholar 

  6. D. W. Kim, Y. S. Jeon, T. Y. Eom, M. Y. Suh, C. H. Lee, J. Radioanal. Nucl. Chem., 150 (1991) 417.

    CAS  Google Scholar 

  7. D. W. Kim, C. P. Hong, C. S. Kim, Y. K. Jeong, Y. S. Jeon, J. K. Lee, J. Radioanal. Nucl. Chem., 220 (1997) 229.

    Article  CAS  Google Scholar 

  8. R. Delgado, Y. Sun, R. J. Motekaitis, A. E. Martell, Inorg. Chem., 32 (1993) 3320.

    Article  CAS  Google Scholar 

  9. T. Kusama, H. Hayatsu, Chem. Pharm. Bull., 18 (1970) 319.

    CAS  Google Scholar 

  10. D. W. Kim, C. S. Kim, K. Y. Choi, T. S. Kim, J. Korean Chem. Soc., 36 (1992) 955.

    CAS  Google Scholar 

  11. C. S. Kim, D. W. Kim, Y. S. Chung, K. Y. Choi, Y. I. Lee, C. P. Hong, J. Korean Chem. Soc., 41 (1997) 166.

    CAS  Google Scholar 

  12. K. Dorfner, Ionenaustauscher, Dritte Aufl. Walter de Gruyter, Berlin, 1970, p. 47.

    Google Scholar 

  13. D. W. Kim, C. S. Kim, K. Y. Choi, Y. I. Lee, C. P. Hong, H. S. Kwon, Bull. Korean Chem. Soc., 16 (1995) 716.

    CAS  Google Scholar 

  14. K. Dorfner (Ed.), Ion Exchangers, Walter de Gruyter, Berlin, 1991, p. 1451.

    Google Scholar 

  15. K. Dorfner, Ionenaustauscher, Dritte Aufl. Walter de Gruyter, Berlin, 1970, p. 292.

    Google Scholar 

  16. E. Glueckauf, Trans. Faraday Soc., 54 (1958) 1203.

    Article  CAS  Google Scholar 

  17. T. Oi, K. Kawada, M. Hosoe, H. Kakihana, Separ. Sci. Technol., 26 (1991) 1353.

    CAS  Google Scholar 

  18. S. Fujine, K. Saito, K. Shiba, J. Nucl. Sci. Technol., 20 (1983) 439.

    CAS  Google Scholar 

  19. D. W. Kim, Y. S. Jeon, Y. K. Jeong, M. Y. Suh, K. S. Lee, J. Radioanal. Nucl. Chem., 189 (1995) 219.

    CAS  Google Scholar 

  20. T. Oi, K. Kawada, M. Hosoe, H. Kakihana, Separ. Sci. Technol., 26 (1991) 1353.

    CAS  Google Scholar 

  21. G. D. Klinskii, D. A. Knyazev, G. I. Vlasova, Zh. Fiz. Khim., 48 (1974) 659.

    CAS  Google Scholar 

  22. T. Oi, H. Ogino, M. Hosoe, H. Kakihana, Separ. Sci. Technol., 27 (1992) 631.

    CAS  Google Scholar 

  23. A. Kondoh, T. Oi, M. Hosoe, Separ. Sci. Technol., 31 (1996) 39.

    CAS  Google Scholar 

  24. K. G. Heumann, R. Hoffmann, Angew. Chem., 88 (1976) 54.

    CAS  Google Scholar 

  25. D. A. Lee, J. Inorg. Nucl. Chem., 38 (1976) 161.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, Physical Chemistry Laboratory, College of Natural Sciences, Chungbuk National University, 361-763, Cheongju, Republic of Korea

    D. W. Kim & H. K. Park

  2. Department of Chemistry Education, College of Education, Chungbuk National University, 361-763, Cheongju, Republic of Korea

    C. S. Kim

  3. Division of Chemical Analysis, Korea Atomic Energy Research Institute, 305-606, Daejon, Republic of Korea

    Y. S. Jeon

Authors
  1. D. W. Kim
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. H. K. Park
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. C. S. Kim
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Y. S. Jeon
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Kim, D.W., Park, H.K., Kim, C.S. et al. Separation of lithium isotopes with the N3O2 trimerrifield peptide resin. J Radioanal Nucl Chem 242, 769–772 (1999). https://doi.org/10.1007/BF02347392

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02347392

Keywords

Search

Navigation