Abstract
Non-destructive multi-element determination in environmental samples by neutron-induced prompt γ-ray analysis (PGA) has been investigated. Comparative standardization for the elements including H, B, C, N, Na, Mg, Al, Si, P, S, Cl, K, Ca, Ti, Mn, Fe, Co, Cd, Sm, Gd, Hg by PGA has been carried out using the cold and thermal guided neutron beams of JRR-3M reactor and then several environmental reference materials have been analyzed. Accuracy and precision of better than 20% were found for these elemental analyses except for H, C, N and Cl in biological samples. Detection limits in various environmental matrices were 25 to 820 ng/g for B, Cd, Sm and Gd, 1.1 to 820 μg/g for H, Na, S, Cl, K, Ti, Mn, Co and Hg, and 0.031 to 10% for C, N, Mg, Al, Si, P, Ca and Fe. The present method is being applied to environmental studies of post war Persian Gulf together with INAA and ICP-MS.
Similar content being viewed by others
References
R. E. Chrien, Neutron Radiative Capture,B. J. Allen, I. Bergqvist, R. E. Chrien, D. Gardner, W. P. Poenitz (Eds), Pergamon Press, Oxford, 1984, p. 187.
Z. B. Alfassi, C. Chung (Eds), Prompt Gamma Neutron Activation Analysis, CRC Press, Boca Raton, 1995.
R. M. Lindstrom, C. Yonezawa, Prompt Gamma Neutron Activation Analysis,Z. B. Alfassi, C. Chung (Eds), CRC Press, Boca Raton, 1995, p. 93.
M. Rossbach, Anal. Chem., 63 (1991) 2156.
R. M. Lindstrom, R. Zeisler, D. H. Vincent, R. R. Greenberg, C. A. Stone, E. A. Mackey, D. L. Anderson, D. D. Clark, J. Radional. Nucl. Chem., 167 (1993) 121.
G. Molnár, Zs. Révay, Á. Veres, A. Simonits, H. Rausch, J. Radioanal. Nucl. Chem., 167 (1993) 133.
C. Yonezawa, A. K. Haji Wood, M. Hoshi, Y. Ito, E. Tachikawa, Nucl. Instr. Meth. Phys. Res., A329 (1993) 207.
C. Yonezawa, Anal. Sci., 9 (1993) 185.
C. Yonezawa, M. Magara, H. Sawahata, H. Hoshi, Y. Ito, E. Tachikawa, J. Radional. Nucl. Chem., 193 (1995) 171.
C. Yonezawa, A. K. Haji Wood, Anal. Chem., 67 (1995) 4466.
C. Yonezawa, submitted to Anal. Sci. for publication.
A. Ando, H. Kamioka, S. Terashima, S. Itoh, Geochem. J., 23 (1989) 143.
E. A. Mackey, G. E. Gordon, R. M. Lindstrom, D. L. Anderson, Anal. Chem., 63 (1991) 288.
S. Suzuki, S. Hirai, Bunseki Kagaku, 41 (1992) 163.
C. Yonezawa, T. Kurosawa, M. Hoshi, Proc. 31st Annual Meeting on Radioisotopes in the Physical Sciences and Industries, 1994, p. 133.
J. W. Readman, S. W. Fowler, J.-P. Villeneuve, C. Caittini, B. Oregioni, L. D. Mee, Nature, 358 (1992) 662.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Yonezawa, C., Matsue, H. & Hoshi, M. Multi-element analysis of environmental samples by cold and thermal guided neutron induced prompt gamma-ray measurement. J Radioanal Nucl Chem 215, 81–85 (1997). https://doi.org/10.1007/BF02109882
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF02109882