Abstract
A new convenient method has been proposed to synthesize mixed-ligand β-diketonato Tc(III) complexes, using the ligand exchange reaction [Tc(acac)2(CH3CN)2]++L−→[Tc(acac)2L]+ +2CH3CN where L is bza, dpm or dbm. The yield was about 30–40%. UV-visible and IR spectra of these complexes were measured. Characteristic features of the compounds were compared with those of the corresponding complexes of ruthenium.
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A. MUTALIB, PhD thesis, Tohoku University, 1993.
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Mutalib, A., Sekine, T., Omori, T. et al. A new convenient method for the synthesis of mixed-ligand β-diketonato Tc(III) complexes. Journal of Radioanalytical and Nuclear Chemistry, Articles 178, 311–318 (1994). https://doi.org/10.1007/BF02039724
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DOI: https://doi.org/10.1007/BF02039724