Skip to main content
Log in

A new convenient method for the synthesis of mixed-ligand β-diketonato Tc(III) complexes

  • Published:
Journal of Radioanalytical and Nuclear Chemistry Aims and scope Submit manuscript

Abstract

A new convenient method has been proposed to synthesize mixed-ligand β-diketonato Tc(III) complexes, using the ligand exchange reaction [Tc(acac)2(CH3CN)2]++L→[Tc(acac)2L]+ +2CH3CN where L is bza, dpm or dbm. The yield was about 30–40%. UV-visible and IR spectra of these complexes were measured. Characteristic features of the compounds were compared with those of the corresponding complexes of ruthenium.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. U. MAZZI, E. RONCARI, G. BANDOLI, L. MAGON, Transition Met. Chem., 4 (1979) 151.

    Article  Google Scholar 

  2. A. B. PACKARD, S. C. SRIVASTA, P. RICHARD, P. SOM, L. A. RARD, J. Nucl. Med., 23 (1982) 17.

    PubMed  Google Scholar 

  3. G. S. PATTERSON, A. DAVISON, A. G. JONES, C. E. COSTELLO, S. MALEKNIA, Inorg. Chim. Acta, 114 (1986) 141.

    Article  Google Scholar 

  4. K. LEESMEISTER, K. SCHWOCHAU, Nucl. Med. Biol., 19 (1992) 73.

    Google Scholar 

  5. K. LEESMEISTER, K. SCHWOCHAU, J. Label. Com. Radiopharm., 24 (1989) 30.

    Google Scholar 

  6. A. MUTALIB, T. OMORI, K. YOSHIHARA, J. Radioanal. Nucl. Chem., 165 (1992) 19.

    Google Scholar 

  7. A. ENDO, M. KAJITANI, M. MUKAIDA, K. SHIMIZU, G. P. SATO, Inorg. Chim. Acta, 150 (1980) 25.

    Article  Google Scholar 

  8. Y. KASAHARA, Y. HOSHINO, K. SHIMIZU, G. P. SATO, Chem. Lett. (1990) 381.

  9. A. MUTALIB, PhD thesis, Tohoku University, 1993.

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Mutalib, A., Sekine, T., Omori, T. et al. A new convenient method for the synthesis of mixed-ligand β-diketonato Tc(III) complexes. Journal of Radioanalytical and Nuclear Chemistry, Articles 178, 311–318 (1994). https://doi.org/10.1007/BF02039724

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02039724

Keywords

Navigation