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Formation and chemical composition of atmospheric aerosols in an equatorial forest area

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Abstract

The physical properties and the chemical composition of atmospheric aerosols have been studied in an equatorial region in the southern Congo (Africa). Field experiments were conducted between 1978 and 1983 in the equatorial forest of the Mayombe during periods where the influence of biomass burning was minimum. The results indicate that the forest is a net source of both fine particles resulting primarily from gas-to-particle conversion and coarse particles produced by mechanical processes. Carbonaceous matter is the major component of these biogenic particles but the forest is also a significant source of sulfate, nitrate, ammonium and potassium. Half of this carbon is attached to submicron particles and likely derives from organic gaseous precursors naturally emitted by the local biosphere.

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References

  • Appel, B. R., Colodny, P., and Wesolowski, J. J., 1976, Analysis of carbonaceous materials in Southern California atmospheric aerosols, Envi. Sci. Tech. 10, 359–363.

    Google Scholar 

  • Artaxo-Netto, P., 1986, The emission of aerosol by plants: a receptor model approach, 2nd International Symposium on Biosphere-Atmosphere Exchanges, Mainz, March 16–22.

  • Artaxo, N. P., Storms, H., Bruynseels, F., Van Grieken, R. and Maenhaut, W., 1987, Composition and sources of aerosols from the Amazon basin, J. Geophys. Res. in press.

  • Bonsang, B., Kanakidou, M., and Lambert, G., 1986, Vertical profiles of nonmethane hydrocarbons in the troposphere, application to the indirect determination of OH radicals, in: 2nd French-German Workshop on the Study of Chemical Reactions with Tropospheric Interest, Viviers, France.

  • Bowen, H. J. M., 1969, Environmental Chemistry of the Elements, Academic Press, New York.

    Google Scholar 

  • Butor, J. F., Legal, J., Renoux, A., and Madelaine, G., 1978, Size distribution of marine aerosol (Ramancap and thermocline expedition), Chemosphere 8, 687–690.

    Google Scholar 

  • Cachier, H., Buat-Ménard, P., Fontugne, M., and Rancher, J., 1985, Carbonaceous aerosols in the tropics: source terms and strengths using concentration and stable carbon isotopes measurements. J. Atmos. Chem. 3, 469–489.

    Google Scholar 

  • Cachier, H., Buat-Ménard, P., Fontugne, M., and Chesselet, R., 1986, Long-range transport of continentally-derived particulate carbon in the marine atmosphere: evidence from stable carbon isotope studies, Tellus 38B, 161–177.

    Google Scholar 

  • Cachier, H., 1987, Atmospheric particulate carbon cycle, Evidence from isotope measurements (in French), Thèse de doctorat d'état, Université de Paris VII, 230 pp.

  • Clairac, B., 1986, L'aérosol en forêt tropicale humide d'Afrique. Application aux échanges entre la forêt et son environnement (in French), Thèse de doctorat d'état No. 1266, Université Paul Sabatier, Toulouse.

  • Cros, B., Lopez, A., and Fontan, J., 1981, Estimation of the A.N. source intensity in rural equatorial Africa, Atm. Environ. 15, 83–90.

    Google Scholar 

  • Cros, B., Delmas, R., Clairac, B., and Fontan, J., 1986, Vertical distribution of ozone in the lower atmosphere in equatorial Africa, 2nd International Symposium on Biosphere-Atmosphere Exchanges, Mainz Frg, March 16–22.

  • Crozat, G., 1979. Sur l'émission d'un aérosol riche en potassium par la forêt équatoriale, Tellus 31, 52–57.

    Google Scholar 

  • Crutzen, P. J., Delany, A. C., Greenberg, J., Haagenson, P., Heidt, L., Lueb, R., Pollock, W., Seiler, W., Wartburg, A., and Zimmerman, P., 1985, Tropospheric chemical composition measurements in Brazil during the dry season, J. Atmos. Chem. 2, 233–256.

    Google Scholar 

  • Delmas, R., Baudet, J., Servant, J., and Baziard, Y., 1980, Emissions and concentrations of hydrogen sulfide in the air of the tropical forest of the Ivory Coast and of temperate regions in France, J. Geophys. Res. 85, 4468–4474.

    Google Scholar 

  • Delmas, R. and Servant, J., 1982, The origins of sulfur compounds in the atmosphere of a zone of high productivity (Gulf of Guinea), J. Geophys. Res. 87, 11019–11026.

    Google Scholar 

  • Delmas, R. and Servant, J., 1983, Atmospheric balance of sulfur above an equatorial forest, Tellus 35B, 110–120.

    Google Scholar 

  • Delmas, R. and Servant, J., 1987, Echanges biosphere-atmosphere d'azote et de soufre enzone intertropicale. Transferts entre les écosystèmes forêt et savane en Afrique de l'Ouest, Atmos. Res. 21, 53–74.

    Google Scholar 

  • Duce, R. A., 1978, Speculations on the budget of particulate and vapor phase non-methane organic carbon in the global troposphere, Pageoph. 116, 244–273.

    Google Scholar 

  • Duce, R. A., Mohnen, V. A., Zimmerman, P. R., Grosjean, D., Cautreels, W., Chatfield, R., Jaenicke, R., Ogren, J. A., Pellizari, E. D., and Wallace, G. T., 1983, Organic material in the global troposphere, Rev. Geophys. Space Phys. 21, 921–952.

    Google Scholar 

  • Farquhar, G. D., Firth, P. M., Wetscelar, R., and Weir, B., 1980, On the gaseous exchange of ammonia between leaves and the environment: Determination of the ammonia compensation point, Plant Physiol. 66, 710–714.

    Google Scholar 

  • Flohn, H., 1969, Local wind systems, in World Survey of Climatology, General Climatology vol. 2, Elsevier, Amsterdam.

    Google Scholar 

  • Fontan, J., 1964, Le dosage des radioéléments gazeux donnant des produits radioactifs de filiation. Son application à la mesure de la radioactivité naturelle de l'atmosphère. Thèse de doctorate es sciences no 218, Université Paul Sabatier (in french), Toulouse.

  • Greenberg, J. P. and Zimmerman, P. R., 1984, Nonmethane hydrocarbons in remote tropical continental and marine atmospheres, J. Geophys. Res. 89, 4767–4778.

    Google Scholar 

  • Gregory, G. L., Harris, R. C., Talbot, R. W., Rasmussen, R. A., Garstang, M., Andreae, M. O., Hinton, R. R., Browell, E. V., Beck, S. M., Sebacher, D. I., Khalil, M. A. K., Ferek, R. J., and Harriss, S. V., 1986, Air chemistry over the tropical forest of Guyana, J. Geophys. Res. 91, 8603–8612.

    Google Scholar 

  • Hogan, A. W., 1968, An experiment illustrating that gas-conversion by solar radiation is a major influence in the diurnal variation of A.N. concentrations, Atmos. Environ. 2, 599–601.

    Google Scholar 

  • Hooker, C. L., Westberg, H. H., and Sheppard, J. C., 1985, Determination of carbon balances for smog chamber terpenes oxidation experiments using a C-14 tracer technique, J. Atmos. Chem. 2, 415–433.

    Google Scholar 

  • Kapadia, 1980, Data reduction techniques for aerosol size distribution measurements of atmospheric aerosols and test of the theorie of self pressuring size distribution, J. Atmos. Sci. 26, 603–608.

    Google Scholar 

  • Lawson, D. R. and Winchester, J. W., 1979, Atmospheric sulfur aerosol concentrations and characteristics from the South American Continent, Science 205, 1267–1269.

    Google Scholar 

  • Liu, B. Y. H., Pui, D. Y. H., and Kapadia, A., 1976, Electrical aerosol analyser: history principal and data reduction, Aerosol Measurement Workshop, University of Florida, Gainsville, U.S.A., March 24–26.

  • Lodge, J. P., Machado, P. A., Pate, J. B., Sheesley, D. C., and Wartburg, A. F., 1974, Atmospheric trace chemistry in the American humid tropics, Tellus 26, 250–259.

    Google Scholar 

  • Logan, J. A., Prather, M. J., Wofsy, S. C., and McElroy, M. B., 1981, Tropospheric chemistry: a global perspective, J. Geophys. Res. 86, 7210–7254.

    Google Scholar 

  • Logan, J. A., 1983, Nitrogen oxides in the troposphere: global and regional budgests, J. Geophys. Res. 88, 10785–10807.

    Google Scholar 

  • Maley, J., 1982, Dust, clouds, rain types and climatic variations in tropical North Africa, Quatern. Res. 18, 1–16.

    Google Scholar 

  • Marenco, A. and Delaunay, J. C., 1980, Experimental evidence of natural sources of CO from measurements in the troposphere, J. Geophys. Res. 85, 5599–5613.

    Google Scholar 

  • Orsini, C. Q., Netto, P. A., and Tabacniks, M. H., 1982, Preliminary data on atmospheric aerosols of the Amazon basin, Atmos. Environ. 16–9, 2177–2181.

    Google Scholar 

  • Podzimeck, J., 1980, Advance in marine aerosol research, J. Rech. Atm. 14–1, 35–61.

    Google Scholar 

  • Rasmussen, J. A., 1970, Isoprene identified as a forest type emission to the atmosphere, Environ. Sci. Technol. 4, 667–671.

    Google Scholar 

  • Schneider, J. K., Gagosian, R. B., Cochran, J. K., and Trull, T. W., 1983, Particle size distributions of n-alkanes and Pb-210 in aerosols off the coast of Peru, Nature 304, 429–432.

    Google Scholar 

  • Schnell, R. C. and Vali, G., 1973, World-wide source of leaf-derived freezing nuclei, Nature 246, 212–213.

    Google Scholar 

  • Servant, J., Delmas, R., Rancher, J., and Rodriguez, J., 1984, Aspects of the cycle of inorganic nitrogen compounds in the tropical rain forest of the Ivory Coast, J. Atmos. Chem. 1, 391–401.

    Google Scholar 

  • Talbot, R. W., Andreae, M. O., Andreae, T. W., and Harriss, R. C., 1987, Regional aerosol chemistry of the Amazon basin during the dry season, J. Geophys. Res. in press.

  • Went, F. W., 1964, The nature of Aitken condensation nuclei in the atmosphere, Proc. Nat. Ac. Sci. 51, 1259–1267.

    Google Scholar 

  • Whitby, K. T., 1978, The physical characteristics of sulfur aerosols, Atmos. Environ. 12, 135–159.

    Google Scholar 

  • Wolff, G. T. and Korsog, P. E., 1985, Estimates of the contributions of sources to inhalable particulate concentrations in Detroit, Atmos. Environ. 19, 1399–1409.

    Google Scholar 

  • Zenehelsky, S. and Youssefi, M., 1979, Natural organic atmospheric aerosols of terrestrial origin, Rev. Geophys. and Space Phys. 17–3, 459–462.

    Google Scholar 

  • Zimmerman, P. R., Chatfield, R. B., Fishman, J., Crutzen, P. J., and Hanst, P. L., 1978, Estimates on the production of CO and H2 from the oxidation of hydrocarbon emissions from vegetation, Geophys. Res. Lett. 5, 679–682.

    Google Scholar 

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Clairac, B., Delmas, R., Cros, B. et al. Formation and chemical composition of atmospheric aerosols in an equatorial forest area. J Atmos Chem 6, 301–322 (1988). https://doi.org/10.1007/BF00051594

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  • DOI: https://doi.org/10.1007/BF00051594

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