Abstract
The formation of nanocrystals after implantation of silver alone as well as together with the halogen ions Cl, Br and I into a SiO2 layer of about 100 nm was studied by X-ray diffraction and transmission electron microscopy. The co-implantation of Ag and Cl or Br results in the formation of cubic AgX crystals which are stable in size under annealing. The co-implantation of Ag and I as well as single Ag implantation result in Ag crystallites, which grow under annealing. The annealing procedure causes a redistribution of the particles within the layer.
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References
A. P. Alivisatos, Science 271 (1996) 933.
M. G. Bawendi, M. L. Steigerwald and L. E. Brus, Annu. Rev. Phys. Chem. 41 (1990) 477.
K. C. Grabar, R. G. Freeman, M. B. Hommer and M. J. Natan, Anal. Chem. 67 (1995) 735.
R. F. Haglund Jr, L. Yang, R. H. Magruder III, C. W. White, R. A. Zuhr, L. Yang, R. Dorsinville and R. R. Alfano, Nucl. Instrum. Methods B 91 (1994) 493.
C. Flytzanis, F. Hache, M. C. Klein, D. Ricard and Ph. Roussignol, Prog. Opt. 29 (1991) 321.
P. V. Kamat, Chem. Rev. 93 (1993) 267.
R. A. Wood, P. D. Townsend, N. D. Skelland, D. E. Hole, J. Barton and C. N. Afonso, J. Appl. Phys. 74 (1993) 5754.
K. P. Johansson, A. P. Marchetti and G. L. McLendon, J. Phys. Chem. 96 (1992) 2873.
A. Henglein, M. Gutierrez, H. Weller, A. Fojtik and J. JirkovskÝ, Ber. Bunsenges. Phys. Chem. 93 (1989) 593.
A. Hagfeldt and M. GrÄtzel, Chem. Rev. 95 (1995) 49.
H. Weller, Angew. Chem. 105 (1993) 43.
A. Henglein, Chem. Rev. 89 (1989) 1861.
G. A. Ozin, A. Kuperman and A. Stein, Angew. Chem. 28 (1989) 359.
J. F. Ziegler, J. P. Biersack and U. Littmark, “The stopping and Range of Ions in solids”, Vol. 1 (Pergamon Press, New York, 1985).
Joint Committee on Powder Diffraction Standards, “Powder diffraction FIle (PDF-2)”, (International Center for Diffraction Data, Newton Square, PA, 1995), Set 44.
J. P. Eberhart, “Structural and chemical analysis of materials” (Wiley, Chichester, West Sussex, 1995) p. 203.
H. P. Klug and L. E. Alexander, “X-ray diffraction procedures” (Wiley, New York, 1974) pp. 656-687.
P. Klimanek, Thesis, Technische Universität Bergakademie Freiberg (1992), Chap. 4.
G. Burns, “Solid state physics” (Academic Press, Orlando, FL, 1985). pp. 129-140, p. 177.
“CRC handbook of chemistry and physics” (CRC Press, Boca Raton, FL, 1992-1993).
N. Matsunami, H. Hosono, Appl. Phys. Lett. 63 (1993) 2050.
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Matz, W., Pham, M.T. & Mucklich, A. Nanometre-sized silver halides entrapped in SiO2 matrices. Journal of Materials Science 33, 155–159 (1998). https://doi.org/10.1023/A:1004310100054
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DOI: https://doi.org/10.1023/A:1004310100054