Abstract
Superferritic stainless steels become embrittled when aged in a temperature interval around 475 °C, This phenomenon has been studied in the alloy Fe-28Cr-2Mo-4Ni-Nb by measuring the decrease in the energy absorbed in the impact test as a function of ageing time at 475 °C. The change which occurs in the microstructure has been studied by small-angle neutron scattering. It is shown that ageing at 475 °C produces the decomposition of the alloy in zones rich in chromium via spinodal decomposition. The high rate of embrittlement observed, compared with that which occurs in Fe-Cr binary alloys of similar chromium content, is related to a faster development of the spinodal decomposition in the steel studied.
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References
M. A. Streitcher,Corrosion 30 (1974) 77.
T. J. Nichol,Met. Trans. A 8A (1977) 229.
M. J. Blackburn andJ. Nutting,J. Iron Steel Inst. 202 (1964) 610.
M. J. Marcinkowski, R. M. Fisher andA. Szirmae,Trans. TMS-AIME 230 (1964) 676.
R. Lagneborg,Acta Polytech. Scand. 62 (1967) 1.
J. C. LaSalle andL. H. Schwartz,Acta Metall. 34 (1986) 989.
M. Anglada, M. Nasarre andJ. A. Planell,Scripta Metall. 21 (1987) 931.
W. C. Leslie, “The Physical Metallurgy of Steels”, (McGraw-Hill, Tokyo, 1982).
T. D. Nys andP. M. Gielen,Met. Trans. 2 (1971) 1423.
T. J. Nichol, A. Datta andG. Aggen,ibid. 11A (1980) 573.
H. D. Solomon andLevinson,Acta Metall. 26 (1978) 429.
M. Hillert,ibid. 9 (1961) 525.
J. W. Cahn,ibid. 11 (1963) 1275.
H. E. Cook,ibid. 18 (1970) 297.
J. S. Langer, M. Baron andH. D. Miller,Phys. Rev. 11A (1975) 1417.
T. Nishizawa, M. Hasebe andM. Ko,Acta Metall. 27 (1971) 817.
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Isalgué, A., Anglada, M., Rodríguez-Carvajal, J. et al. Study of the spinodal decomposition of an Fe-28Cr-2Mo-4Ni-Nb alloy by small-angle neutron scattering. J Mater Sci 25, 4977–4980 (1990). https://doi.org/10.1007/BF00580116
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DOI: https://doi.org/10.1007/BF00580116