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δ-FeO(OH) and its solid solutions

Part 1 Preparation and crystal chemistry

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Abstract

δ-FeO(OH)-type solid solutions have been synthesized with compositions Fe1−x M x O1−x (OH)1+x ranging up tox=0.10 for M=Ca,x=0.35 for M=Mg or Cd andx=0.40 for M=Zn. The phases are characterized by X-ray diffraction and transmission electron microscope studies. A structural model giving satisfactory intensity agreement is postulated for Fe1−x Zn x O1−x (OH)1+x . In this model, Zn2+ ions are situated in the 0 0 0 octahedral sites of space group D 33d -P¯3ml while the Fe3+ ions are almost equally distributed among both octahedral sites (0 0 0 and 0 0 1/2).

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Authors and Affiliations

  1. Xerox Corporation, Xerox Square, W114, 14644, Rochester, New York, USA

    Olaf Muller, Robert Wilson & William Krakow

  2. Department of Chemical Engineering, Pennsylvania State University, 16802, University Park, Pennsylvania, USA

    Robert Wilson

  3. Thomas J. Watson Research Center, IBM Corporation, P.O. Box 218, 10598, Yorktown Heights, New York, USA

    William Krakow

Authors
  1. Olaf Muller
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  2. Robert Wilson
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  3. William Krakow
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Muller, O., Wilson, R. & Krakow, W. δ-FeO(OH) and its solid solutions. J Mater Sci 14, 2929–2936 (1979). https://doi.org/10.1007/BF00611477

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  • DOI: https://doi.org/10.1007/BF00611477

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