Abstract
Crown amide (1) forms a stoicheiometric 1:1 inclusion complex with water, the X-ray crystal structure of which is reported. Crystals of1 · H2O are triclinic, space groupP1, witha=7.503(1),b=11.394(3),c=13.443(2) Å, α=107.066(18), β=96.627(10), γ=106.377(14)°, andZ=2.R F =0.039 for 1697 MoKα reflections [I>3σ(I)] measured at 24°C. The structure features a hydrogen bonded hostguest relationship with concrete1 · H2O units. Hydrogen bonds are between the water oxygen and O(4), N(4), respectively. The crystal packing shows a cavity arrangement of four ligands around each water molecule.
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Supplementary Data relating to this article are deposited with the British Library as Supplementary Publication No. SUP 82055 (16 pages).
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Weber, E., Newkome, G.R., Fronczek, F.R. et al. Inclusion of water by a crown amide. First crystal structure of a respective host-guest combination. Journal of Inclusion Phenomena 6, 1–7 (1988). https://doi.org/10.1007/BF00659363
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DOI: https://doi.org/10.1007/BF00659363