Abstract
Five new bis(benzo-15-crown-5) derivatives with different connecting groups were synthesized. Potassium ion-selective PVC membrane electrodes based on these bis(crown ether)s were prepared and their selective properties were measured. The results showed that most of these electrodes are stable over a wide pH range and their selectivity coefficients were better than those of an electrode based on natural valinomycin.
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Li, A., Zhang, Z., Wu, Y. et al. The synthesis of bis(benzo-15-crown-5) derivatives and their use in potassium-PVC membrane electrodes. J Incl Phenom Macrocycl Chem 15, 317–327 (1993). https://doi.org/10.1007/BF00708749
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DOI: https://doi.org/10.1007/BF00708749