Skip to main content
SpringerLink
Log in

The effect of Fe(II) ions on the 1,10-phenanthroline and neocuproine intercalates of γ-zirconium phosphate

  • Published:
Journal of inclusion phenomena and molecular recognition in chemistry Aims and scope Submit manuscript

Abstract

1,10-Phenanthroline (phen), 2,9-dimethyl-1,10-phenanthroline (neocuproine), and 4,7-dimethyl-1,10-phenanthroline have been intercalated between layers of γ-zirconium phosphate (γ-ZrP). The observed interlayer distances are not a simple function of the size of guest molecules. Despite the fact that γ-ZrP takes up very few Fe2+ ions, the phen and neocuproine intercalates do take up some Fe2+ ions without further changes in the interlayer distances. The chemical environments around Fe2+ ions between layers of the intercalates were investigated by57Fe Mössbauer spectroscopy. A fairly large fraction of the Fe2+ ions was found to be in a high-spin state. The low-spin [Fe(phen)3]2+ ions are also ion exchanged on γ-ZrP, with the expansion of the interlayer up to 19.9 Å.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. I. Tomita, C. Takeo, and Y. Hasegawa:J. Incl. Phenom. 9, 315 (1990).

    Google Scholar 

  2. A. N. Christensen, E. K. Andersen, I. G. K. Andersen, G. Alberti, M. Nielsen and M. S. Lehmann:Acta Chem. Scand. 44, 865 (1990).

    Google Scholar 

  3. U. Costantino and R. Vivani:New Developments in Ion Exchange (Eds. M. Abe, T. Kataoka, T. Suzuki), p. 205, Kodansha-Elsevier (1991).

    Google Scholar 

  4. S. Yamanaka and M. Tanaka:J. Inorg. Nucl. Chem. 41, 45 (1979).

    Google Scholar 

  5. A. Clearfield and J. M. Graces:J. Inorg. Nucl. Chem. 41, 879 (1979).

    Google Scholar 

  6. A. Clearfield, R. H. Blessing and J. A. Stynes:J. Inorg. Nucl. Chem. 30, 2249 (1968).

    Google Scholar 

  7. G. Alberti and U. Costantino:Intercalation Chemistry (Eds. M. S. Wittingham and J. A. Jacobson), Ch. 5, Academic Press (1982).

  8. F. M. Van Metoi and H. M. Neumann:J. Am. Chem. Soc. 98, 1382 (1976).

    Google Scholar 

  9. C. Ferragina, M. A. Massucci, and A. A. G. Tomlinson:J. Chem. Soc. Dalton Trans. 1191 (1990).

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, Ochanomizu University, 112, Otsuka, Tokyo, Japan

    Isao Tomita & Kayo Sasaki

  2. Department of Industrial Chemistry, Faculty of Technology, Tokyo University of Agriculture and Technology, 184, Koganei, Tokyo, Japan

    Yoshitsugu Hasegawa

  3. Department of Chemistry, Faculty of Science, Toho University, Miyama, 274, Funabashi, Chiba, Japan

    Masuo Takeda & Masashi Takahashi

Authors
  1. Isao Tomita
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Kayo Sasaki
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Yoshitsugu Hasegawa
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Masuo Takeda
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Masashi Takahashi
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Tomita, I., Sasaki, K., Hasegawa, Y. et al. The effect of Fe(II) ions on the 1,10-phenanthroline and neocuproine intercalates of γ-zirconium phosphate. J Incl Phenom Macrocycl Chem 14, 317–326 (1992). https://doi.org/10.1007/BF01045990

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01045990

Key words

Search

Navigation