Skip to main content
SpringerLink
Log in

Dependence of intramolecular valence delocalization on crystal form in mixed-valence trinuclear iron phenylacetate [Fe III2 FeIIO(PhCH2CO2)6(py)3]

  • Published:
Hyperfine Interactions Aims and scope Submit manuscript

Abstract

A dependence of intramolecular valence delocalization on crystal form in mixed-valence trinuclear iron phenylacetate [Fe III2 FeIIO(PhCH2CO2)6(py)3] was found. This complex was obtained in two different crystal forms: a columnar and a needle crystal form. Mössbauer spectra of the columnar crystals show a temperature-dependent valence delocalization, while the needle crystals show a trapped mixed-valence state from a lower temperature up to room temperature.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. H.G. Jang, K. Kaji, M. Sorai, R.J. Wittebort, S.J. Geib, A.L. Rheingold and D.N. Hendrickson, Inorg. Chem. 29(1990)3547, and references cited therein.

    Google Scholar 

  2. T. Nakamoto, M. Katada and H. Sano, Chem. Lett. (1990)225.

  3. T. Nakamoto, M. Katada and H. Sano, Chem. Lett. (1991)1323.

  4. T. Nakamoto, M. Katada and H. Sano, Hyp. Int. 68(1991)233.

    Google Scholar 

  5. S. Nakashima, Y. Masuda, I. Motoyama and H. Sano, Bull. Chem. Soc. Jpn. 60(1987)1673.

    Google Scholar 

  6. S. Nakashima and H. Sano, Chem. Lett. (1989)1075.

  7. M. Yoshida, T. Nakamoto, S. Kawata, M. Katada and H. Sano, these Proceedings, Hyp. Int. 84(1994)589.

    Google Scholar 

  8. H. Gilman (ed.),Organic Syntheses, Collective Vol. I (Reinhold, New York, 1956) pp. 436–438.

    Google Scholar 

  9. D. Lupu and R. Ripan, Rev. Roum. Chim. 16(1971)43.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, Tokyo Metropolitan University, Minamiohsawa, Hachioji, 192-03, Tokyo, Japan

    M. Yoshida, T. Nakamoto, S. Kawata & H. Sano

  2. Radioisotope Research Center, Tokyo Metropolitan University, Minamiohsawa, Hachioji, 192-03, Tokyo, Japan

    M. Katada

Authors
  1. M. Yoshida
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. T. Nakamoto
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. S. Kawata
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. M. Katada
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. H. Sano
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Yoshida, M., Nakamoto, T., Kawata, S. et al. Dependence of intramolecular valence delocalization on crystal form in mixed-valence trinuclear iron phenylacetate [Fe III2 FeIIO(PhCH2CO2)6(py)3]. Hyperfine Interact 84, 583–588 (1994). https://doi.org/10.1007/BF02060713

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02060713

Keywords

Search

Navigation