Abstract
We have carried out μSR experiments on [Co(NH3)6]Cl3 and [Co(ND3)6]Cl3. At 293 K, all the muons implanted into the complexes were in the diamagnetic state. The observed Gaussian-type muon spin relaxation function proved that the internal magnetic field was caused by nuclear dipole moments of the atoms in the complexes. In addition, another exponential-type muon spin relaxation function was observed in [Co(ND3)6]Cl3 below 50 K.
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M.K. Kubo, Y. Sakai, T. Tominaga and K. Nagamine, J. Radioanal. Nucl. Chem. Lett. 136(1989)61.
G.R. Murray, Jr. and J.S. Waugh, J. Chem. Phys. 29(1958)207.
P.H. Kim, J. Phys. Soc. Jpn. 15(1960)445.
Inorganic Syntheses, Vol. 2 (McGraw-Hill, New York, 1946) p. 216.
B.D. Powell and N. Sheppard, Chemistry & Industry (1956) 314.
H. Block and V. Gold, J. Chem. Soc. (1959) 966.
Y. Sakai, M.K. Kubo, T. Tominaga, K. Nishiyama and K. Nagamine, J. Radioanal. Nucl. Chem. Lett. 127(1988)425.
R.S. Hayano, Y.J. Uemura, J. Imazato, N. Nishida, T. Yamazaki and R. Kubo, Phys. Rev. B20(1979)850.
T. Ito and T. Chiba, Bull. Chem. Soc. Jpn. 42(1969)108.
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Kagetsu, H., Shioyasu, N., Fukunishi, N. et al. Positive muons in [Co(NH3)6]Cl3 and [Co(ND3)6]Cl3 . Hyperfine Interact 84, 517–520 (1994). https://doi.org/10.1007/BF02060702
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DOI: https://doi.org/10.1007/BF02060702