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conversion electron Mössbauer study of low carbon steel polarized in aqueous sulfate solution containing sulfite in low concentration

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Abstract

The passivation of low carbon steel was studied in aqueous solution of 0.5 M Na2SO4+0.001 M NaHSO3 at pH=3.5 and 6.5. The found major components at pH-3.5 were: γ-FeOOH and Fe3C, and also FeSO4.H2O could be identified on the surface of the low carbon steel as a minor component. At pH-6.5, the passive film contained only amorphous iron(III)-oxide or oxyhydroxide.

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Authors and Affiliations

  1. Department of Physical Chemistry, Eötvös L. University, P.O. Box 32, Budapest, Hungary

    Cs. Vértes & M. Lakatos-Varsányi

  2. Department of Nuclear Chemistry, Eötvös L. University, P.O. Box 32, 1518, Budapest, Hungary

    A. Vértes & E. Kuzmann

  3. Institute of Inorganic and Analytical Chemistry, University of Mainz, D-6500, Mainz, Germany

    W. Meisel & P. Gütlich

Authors
  1. Cs. Vértes
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  2. M. Lakatos-Varsányi
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  3. A. Vértes
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  4. E. Kuzmann
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  5. W. Meisel
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  6. P. Gütlich
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Vértes, C., Lakatos-Varsányi, M., Vértes, A. et al. conversion electron Mössbauer study of low carbon steel polarized in aqueous sulfate solution containing sulfite in low concentration. Hyperfine Interact 69, 731–734 (1992). https://doi.org/10.1007/BF02401930

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  • DOI: https://doi.org/10.1007/BF02401930

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