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A Mössbauer study of iron-containing phases in a vanadium oxide catalyst for the oxidation of sulphur dioxide in sulphuric acid production

  • Surface Phenomena, Catalysis, Corrosion
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Abstract

The iron-containing phases in fresh and partly deactivated vanadium oxide catalyst are identified by Mössbauer spectroscopy. As a result of exploitation of the catalyst the new phases of Fe3O4, FeSO4 and Fe2(SO4)3 alongwith presence of α-Fe2O3 are formed. The Mössbauer spectroscopy presents new possibilities for studying the composition changes in iron-containing phases, and provides a tool to reveal the reasons leading to deactivation of industrial vanadium catalysts.

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Authors and Affiliations

  1. Institute of General and Inorganic Chemistry, Academy of Sciences of Bulgaria, B-1040, Sofia

    D. Klissurski, L. Makedonski & V. Bluskov

  2. Institute of Kinetics and Catalysis, Academy of Sciences of Bulgaria, B-1040, Sofia

    I. Mitov

Authors
  1. D. Klissurski
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  2. L. Makedonski
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  3. I. Mitov
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  4. V. Bluskov
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Klissurski, D., Makedonski, L., Mitov, I. et al. A Mössbauer study of iron-containing phases in a vanadium oxide catalyst for the oxidation of sulphur dioxide in sulphuric acid production. Hyperfine Interact 57, 1919–1922 (1990). https://doi.org/10.1007/BF02405742

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  • DOI: https://doi.org/10.1007/BF02405742

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