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Mixed-valence states of 11, 1111-dialkyl- and 11, 1111-bis(methylbenzyl)biferrocenium triiodides

  • Chemical Structure and Bonding
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Abstract

It was found that the packing of cations and anions influences the electronic structures of mixed-valence binuclear ferrocene derivatives. Temperature-dependence of the mixed-valence state of 11, 1111-diisobutylbiferrocenium triiodide was observed in a crystalline state, whereas only a trapped-valence state was found in a dispersed state. The packing effect was also observed for a series of 11, 1111-dialkyl- and 11, 1111-bis(methylbenzyl)biferrocenium triiodides by means of ESR spectroscopy.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, Tokyo Metropolitan University, Fukasawa, Setagaya-ku, 158, Tokyo, Japan

    Satoru Nakashima, Yuichi Masuda & Hirotoshi Sano

  2. Department of Chemistry, Faculty of Engineering, Kanagawa University, Rokkakubashi, Kanagawa-ku, 221, Yokohama, Japan

    Izumi Motoyama

Authors
  1. Satoru Nakashima
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  2. Yuichi Masuda
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  3. Izumi Motoyama
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  4. Hirotoshi Sano
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Nakashima, S., Masuda, Y., Motoyama, I. et al. Mixed-valence states of 11, 1111-dialkyl- and 11, 1111-bis(methylbenzyl)biferrocenium triiodides. Hyperfine Interact 40, 319–322 (1988). https://doi.org/10.1007/BF02049107

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