Conclusions
During the exposure with sodium in ampule conditions over 2–3 days at 350–500°C and 1 h at 700°C of mineral vacuum oil, not containing aromatic hydrocarbons, carbon acetylide is formed to the amount of ∼20%, (550°C) scaled to the carbon in the original oil.
Sodium acetylide, which is an intermediate product, at 550–700°C in the presence of excess sodium is decomposed, and the change of its content by 1.5–2 orders takes place after 1 h at 700°C and after 2 days at 550°C.
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Additional information
Translated from Atomnaya Énergiya, Vol. 56, No. 4, pp. 231–232, April, 1984.
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Kovalev, Y.P., Gavrilova, N.V. Kinetics of the behavior of sodium acetylide in a sodium-mineral oil system. At Energy 56, 258–260 (1984). https://doi.org/10.1007/BF01124192
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DOI: https://doi.org/10.1007/BF01124192