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Cathode-catalyzed transesterification of alkylphosphonates

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Abstract

The cathodic electrolysis of aliphatic alcohols and alkylphosphonates in acetonitrile with 0.5 N Et4NClO4 as the base electrolyte leads to mono- and ditransesterified phosphonates. The yield and ratio of these products is a function of the nature of the starting reagents and amount of current passed.

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    M. E. Niyazymbetov, B. Kostizella, I. Keitel & K. H. Schwartz

  2. Central Organic Chemistry Institute, Academy of Sciences of the German Democratic Republic, Berlin

    M. E. Niyazymbetov, B. Kostizella, I. Keitel & K. H. Schwartz

Authors
  1. M. E. Niyazymbetov
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  2. B. Kostizella
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  3. I. Keitel
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  4. K. H. Schwartz
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 200–204, January, 1991.

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Niyazymbetov, M.E., Kostizella, B., Keitel, I. et al. Cathode-catalyzed transesterification of alkylphosphonates. Russ Chem Bull 40, 182–186 (1991). https://doi.org/10.1007/BF00959658

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  • DOI: https://doi.org/10.1007/BF00959658

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