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Formation of spin adducts in the interaction of palladium and titanium superoxo complexes with spin traps

  • Physical Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

The superoxo complexes of palladium Pd(\(O_2 ^{\underset{\raise0.3em\hbox{$\smash{\scriptscriptstyle\cdot}$}}{ - } } \)) and titanium Ti(\(O_2 ^{\underset{\raise0.3em\hbox{$\smash{\scriptscriptstyle\cdot}$}}{ - } } \)) interact with spin traps (cyclic aldonitrones) to form spin adducts. The EPR parameters of these spin adducts differ from those of the spin adduct formed by reaction with the free superoxo complex ion, and depend on the nature of the metal.

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Authors and Affiliations

  1. Institute of Catalysis, Siberian Branch, Academy of Sciences of the USSR, Novosibirsk

    E. P. Talzi & L. B. Volodarskii

  2. Novosibirsk Institute of Organic Chemistry, Siberian Branch, Academy of Sciences of the USSR, Novosibirsk

    E. P. Talzi & L. B. Volodarskii

Authors
  1. E. P. Talzi
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  2. L. B. Volodarskii
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1260–1262, June, 1989.

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Talzi, E.P., Volodarskii, L.B. Formation of spin adducts in the interaction of palladium and titanium superoxo complexes with spin traps. Russ Chem Bull 38, 1147–1149 (1989). https://doi.org/10.1007/BF00957142

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  • DOI: https://doi.org/10.1007/BF00957142

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