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Hydrogen isotope exchange catalyzed by phosphine complexes of palladium

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Bis(triphenylphosphine)bis(trifluoroacetato)palladium in aqueous solutions of trifluoroacetic acid catalyzes the isotope exchange of hydrogen between dihydrogen and the protons of the solvent.

  2. 2.

    Hydrogen exchange proceeds through the formation and decomposition of a hydride complex of palladium, the hydrogen atom in which is capable of exchanging with the protons of the solvent.

  3. 3.

    The introduction of ethylene into the system lowers the rate of the hydrogen exchange reaction, and the presence of a mixture of ethylene and carbon monoxide completely inhibits this reaction.

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Literature cited

  1. V. N. Zudin, V. A. Likholobov, V. M. Nekipelov, V. A. Rogov, M. N. Bredikhin, V. A. Shmachkov, L. A. Sazonov, and Yu. I. Ermakov, Summaries of Papers from 6th All-Union Conference on Catalytic Reactions in the Liquid Phase [in Russian], Alma-Ata (1983), Part 2, p. 131.

  2. V. N. Zudin, G. N. Il'inich, V. A. Likholobov, and Yu. I. Ermakov (Yermakov), J. Chem. Soc., Chem. Commun., p. 545 (1984).

  3. G. Henrici-Olive and S. Olive, Coordination and Catalysis, Verlag-Chemie, New York (1977).

    Google Scholar 

  4. G. Henrici-Olive and S. Olive, J. Mol. Catal.,1, 121 (1976).

    Google Scholar 

  5. A. P. Khrushch, L. A. Tokina, and A. E. Shilov, Kinet. Katal.,7, 901 (1966).

    Google Scholar 

  6. J. Halpern and B. R. James, Can. J. Chem.,44, 671 (1966).

    Google Scholar 

  7. H. E. A. Hann and E. Peters, J. Phys. Chem.,75, 571 (1971).

    Google Scholar 

  8. An. N. Nesmeyanov, Radiochemistry [in Russian], Khimiya, Moscow (1978), p. 31.

    Google Scholar 

  9. V. N. Zudin, V. A. Likholobov, V. M. Mastikhin, O. B. Lapina, and Yu. I. Ermakov, Koord. Khim.,5, 432 (1979).

    Google Scholar 

  10. V. A. Likholobov, N. K. Eremenko, and V. N. Zudin, Izv. Sib. Otd. Akad. Nauk SSSR, Otd. Khim. Nauk, No. 3, 102 (1976).

    Google Scholar 

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Authors and Affiliations

  1. Institute of Catalysis, Siberian Branch, Academy of Sciences of the USSR, Novosibirsk

    V. N. Zudin, V. A. Rogov, V. A. Likholobov, V. A. Shmachkov, L. A. Sazonov & Yu. I. Ermakov

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  1. V. N. Zudin
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  2. V. A. Rogov
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  3. V. A. Likholobov
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  4. V. A. Shmachkov
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  5. L. A. Sazonov
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  6. Yu. I. Ermakov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 8, pp. 1726–1730, August, 1985.

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Zudin, V.N., Rogov, V.A., Likholobov, V.A. et al. Hydrogen isotope exchange catalyzed by phosphine complexes of palladium. Russ Chem Bull 34, 1577–1581 (1985). https://doi.org/10.1007/BF00948495

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  • DOI: https://doi.org/10.1007/BF00948495

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