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Liquid-phase oxidation of cyclohexene under catalysis by lamellar com pounds of graphite and transition-metal chlorides

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Lamellar compounds of graphite with Cu, Co, Mn, Fe, Ni, Mo, and Znchlorides are catalytically active in the liquid-phase oxidation of cyclohexene by molecular oxygen and in the breakdown of cyclohexyl hydroper-oxides. Appreciable quantities of cyclohexene oxide are formed in these reactions on LCG-MoCl5.

  2. 2.

    On the basis of the determined product compositions, and our knowledge of the kinetics of heterogeneously catalyzed liquid-phase oxidation reactions, oxidation in the presence of the LCG must proceed through a radical-chain heterogeneous-homogeneous mechanism.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    N. I. Kovtyukhova, V. M. Belousov, S. V. Mikhalovskii, L. D. Kvacheva, Yu. N. Novikov & M. E. Vol'pin

  2. L. V. Pisarzhevskii Institute of Physical Chemistry, Academy of Sciences of the Ukranian SSR, Kiev

    N. I. Kovtyukhova, V. M. Belousov, S. V. Mikhalovskii, L. D. Kvacheva, Yu. N. Novikov & M. E. Vol'pin

Authors
  1. N. I. Kovtyukhova
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  2. V. M. Belousov
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  3. S. V. Mikhalovskii
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  4. L. D. Kvacheva
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  5. Yu. N. Novikov
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  6. M. E. Vol'pin
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 25–30, January, 1983.

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Kovtyukhova, N.I., Belousov, V.M., Mikhalovskii, S.V. et al. Liquid-phase oxidation of cyclohexene under catalysis by lamellar com pounds of graphite and transition-metal chlorides. Russ Chem Bull 32, 16–20 (1983). https://doi.org/10.1007/BF01167752

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  • DOI: https://doi.org/10.1007/BF01167752

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