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Si-methyl(fluoro)-substituted derivatives of trans-1, 2-disilylethylene

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

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The treatment of trans-l, 2-disilylethylene derivatives of type (CH3)3-nXnSiCH = CHSi(CH3)3-mXm, where X=Cl or OCH3, and n, m=1-3, with 40% HF gave the corresponding fluoro derivatives (CH3)3-nFnSiCH=CHSi(CH3)3-mFm in high yields.

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Literature cited

  1. M. G. Voronkov, O. G. Yarosh, V. A. Pestunovich, M. V. Sigalov, and L. V. Tsvetaeva, Izv. Akad. Nauk SSSR, Ser. Khim.,1974, 2060.

  2. M. G. Voronkov, O. G. Yarosh, L. V. Tsvetaeva, M. V. Sigalov, and R. A. Gromkova, Zh. Obshch. Khim.,44, 1747 (1974).

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 8, pp. 1911–1913, August, 1981.

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Voronkov, M.G., Yarosh, O.G., Shchukina, L.V. et al. Si-methyl(fluoro)-substituted derivatives of trans-1, 2-disilylethylene. Russ Chem Bull 30, 1577–1579 (1981). https://doi.org/10.1007/BF00952225

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  • DOI: https://doi.org/10.1007/BF00952225

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