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NMR spectra and structure of 2-(2′-chloroethoxy)-2-oxa-3-methyl-1,4,2-dioxaphosphane

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The configurations and conformations of a new six-membered phosphorus-containing heterocycle 2-(2′-chloroethoxy)-2-oxa-3-methyl-1,4,2-dioxaphosphane were studied by the NMR method.

  2. 2.

    The value of the geminal SSIC2J31PCH in this compound was determined primarily by the mutual orientation of the proton and phosphoryl groups.

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Literature cited

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Authors and Affiliations

  1. Irkutsk Institute of Organic Chemistry, Siberian Branch of the Academy of Sciences of the USSR, USSR

    M. V. Sigalov, V. A. Pestunovich, V. I. Glukhikh, M. Ya. Khil'ko, V. M. Nikitin, M. F. Larin & B. A. Trofimov

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  1. M. V. Sigalov
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  2. V. A. Pestunovich
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  3. V. I. Glukhikh
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  4. M. Ya. Khil'ko
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  5. V. M. Nikitin
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  6. M. F. Larin
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  7. B. A. Trofimov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 8, pp. 1761–1764, 1975.

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Sigalov, M.V., Pestunovich, V.A., Glukhikh, V.I. et al. NMR spectra and structure of 2-(2′-chloroethoxy)-2-oxa-3-methyl-1,4,2-dioxaphosphane. Russ Chem Bull 24, 1645–1647 (1975). https://doi.org/10.1007/BF01100012

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  • DOI: https://doi.org/10.1007/BF01100012

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