Conclusions
X-ray and electron-microscopic methods were used to study the composition and structure of specimens in the ZrO2-CaO system (12–25% CaO) after prolonged firing at 1100–1420°C.
We established the presence in the aging products of the ordered phasesϕ 1 (CaZr4O9),ϕ (Ca2Zr7O16), andϕ 2 (Ca6Zr19O44).
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References
C. Delamarre and M. Perez y Jorla, “System calcium oxide—hafnium dioxide,” Rev. Hautes Temp. Refract.,2, 313–318 (1965).
C. Delamarre, “Contribution à l'etude de quelques systemes HfO2−MO. Comparaison avec les systèmes correspondants à base de zircone,” Rev. Int. Haut. Temp.,9, 209–224 (1972).
J. G. Allpress, H. J. Rossell, and H. G. Scott, “Fluorite-related phases in the system CaO-HfO2,” Mater. Res. Bull.,9, No. 4, 455–468 (1974).
H. J. Rossell and H. G. Scott, “The structure of the fluorite-related phase Ca2Hf7O16,” J. Solid State Chem.,13, No. 4, 345–352 (1975).
J. G. Allpress and H. J. Rossell, “A microdomain description of defective fluorite-type phases CaxM1−xO2−x (M = Zr, Hf; x=0.1–0.2),” J. Solid State Chem.,15, No. 1, 68–78 (1975).
J. G. Allpress, H. J. Rossell, and H. G. Scott, “Crystal structures of the fluorite-related phases CaHf4O9 and Ca6Hf19O44,” J. Solid State Chem.,14, No. 3, 264–273 (1975).
Yu. A. Pyatenko, “Some quantitative ratios in structures derived from the fluorite type,” Zh. Strukturnoi Khim.,4, No. 5, 708 (1963).
Yu. A. Pyatenko, “Crystal-chemical identification of some intermediate phases in the CaO-HfO2 (ZrO2) and R2O3-TiO2 (ZrO2) systems,” Dokl. Akad. Nauk SSSR,173, No. 3, 634–637 (1967).
T. I. Tien and E. C. Subbarao, “X-ray and electrical conductivity study of the fluorite phase in the system ZrO2-CaO,” J. Chem. Phys.,39, No. 4, 1041–1047 (1963).
R. E. Carter and W. L. Roth, “Conductivity and structure in calcia-stabilized zirconia,” in: Electromotive force measurements in high-temperature systems (Proceedings of symposium), C. B. Alcock (ed.), Institution of Mining and Metallurgy, London (1968), pp. 125–144.
R. E. Carter and W. L. Roth, “Proceedings of a symposium held by the Nuffield Research Group,” Imperial College, London, April (1967).
R. E. Carter and W. L. Roth, “General Electric technical information,” series No. 63 RL3479M, November (1963).
D. Michel, “Etats d'ordre dans la solution solide de type fluorite du systeme zircone-chaux pour la composition 4 ZrO2-CaO,” Mater. Res. Bull.,8, No. 8, 943–949 (1973).
J. R. Hellmann and V. S. Stubican, “The existence and stability of Ca6Zr19O44 compound in the system ZrO2-CaO,” Mater. Res. Bull.,17, No. 4, 459–465 (1982).
J. R. Hellmann and V. S. Stubican, “Stable and metastable phase relations in the system ZrO2-CaO,” J. Amer. Ceram. Soc,66, No. 4, 260 (1983).
W. H. Rhodes and R. E. Carter, “Cationic self-diffusion in calcia-stabilized zirconia,” J. Amer. Ceram. Soc,49, No. 5, 244 (1966).
S. P. Ray and V. S. Stubican, “Fluorite-related ordered compounds in the ZrO2-CaO and ZrO2-Y2O3 systems,” Mater. Res. Bull.,12, No. 5, 549–556 (1977).
D. Michel, “Contribution à l'etude de phenomenon d'ordonancement de defante dans mono ristaux de materiaux refractaires à base d'aluminia et de zircone,” Rev. Int. Haut. Temper. Refract.,9, No. 2, 225–241 (1972).
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Translated from Ogneupory, No. 10, pp. 7–11, October, 1993.
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Gavrish, A.M., Karyakina, É.L., Shulik, I.G. et al. Phase composition and structure of specimens in the ZrO2-CaO system after aging. Refractories 34, 504–509 (1993). https://doi.org/10.1007/BF01295034
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DOI: https://doi.org/10.1007/BF01295034