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Use of a fluorescence method for assessing the properties of polymers and their composites and for adapting their production technology

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Mechanics of Composite Materials Aims and scope

Conclusions

  1. 1.

    Correlation of relaxation and diffusion processes in polymers and their composites with the kinetic patterns shows the possibilities of the fluorescence method for monitoring the process of polymerization of polymeric composites, and hence for adapting their production technology.

  2. 2.

    Analysis of relaxation and diffusion processes in polymeric composites reveals the possibilities of using the fluorescence method not only for assessing their structural features (micrononhomogeneity, stratification) and physical properties such as microviscosity, but also to follow their evolution in the course of the polymerization process.

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Literature cited

  1. J. A. Manson and L. Kh. Sperling, Polymeric Mixtures and Composites [Russian translation], Moscow (1979).

  2. G. M. Gunyaev, Structure and Properties of Polymeric-Fibrous Composites [in Russian], Moscow (1981).

  3. S. Parker, Photoluminescence of Solutions [Russian translation], Moscow (1972).

  4. I. I. Kalechits, M. G. Kuz'min, V. P. Zubob, and V. A. Kabanov, ″Fluorescence quenching study of diffusion processes in polymerizable methyl metacrylate,″ Dokl. Akad. Nauk SSSR,244, No. 5, 1157–1160 (1979).

    Google Scholar 

  5. I. I. Kalechits, M. G. Kuz'min, V. P. Zubob, and V. A. Kabanov, ″Fluorescence quenching study of structure formation in polymerizable methyl methacrylate with addition of a precipitator,″ Dokl. Akad. Nauk SSSR,256, No. 2, 407–410 (1980).

    Google Scholar 

  6. I. I. Kalechits, V. P. Zubov, M. G. Kuz'min, and V. A. Kabanov, ″Fluorescence quenching study of structure formation in polymerizable methyl methacrylate with addition of a dimethyl acrylic ester of ethylene glycol as crosslinking agent,″ Vysokomol. Soedin., Ser. A,26, No. 2, 576–582 (1984).

    Google Scholar 

  7. M. G. Kuz'min and N. A. Sadovskii, ″Study of kinetics of fast reactions of excited molecules by nanosecond pulse fluorimetry,″ Khim. Vys. Énerg.,9, No. 4, 291–310 (1975).

    Google Scholar 

  8. I. I. Kalechits, V. P. Zubov, M. G. Kuz'min, and V. A. Kabanov, ″Study of interactions of macromolecular repeating units in concentrated solutions of poly(methyl methacrylate) by fluorescence quenching,″ Vysokomol. Soedin., Ser. A,26, No. 10, 2118–2135 (1984).

    Google Scholar 

  9. C. H. Lochmuller, A. S. Colborn, M. L. Hunnicutt, and J. M. Harris, ″Bound pyrene excimer photophysics and organization and distribution of reaction sites on silica,″ J. Am. Chem. Soc.,106, 4077–4082 (1984).

    Google Scholar 

  10. E. Kolpin, Fast Reactions in Solutions [in Russian], Moscow (1966).

  11. M. P. Berezin and G. V. Korolev, ″The monolytization stage in the radical-initiated three-dimensional polymerization process,″ Vysokomol. Soedin., Ser. A,22, No. 8, 1872–1877 (1980).

    Google Scholar 

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Translated from Mekhanika Kompozitnykh Materialov, No. 2, pp. 331–336, March–April, 1987.

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Kalechits, I.I., Kuz'min, M.G., Kozlov, P.V. et al. Use of a fluorescence method for assessing the properties of polymers and their composites and for adapting their production technology. Mech Compos Mater 23, 247–251 (1987). https://doi.org/10.1007/BF00606332

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  • DOI: https://doi.org/10.1007/BF00606332

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