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Anomalous rearrangement of 1,2,3-thiadiazoles to 1,2,3-triazoles

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

The rearrangement of 5-amino-1,2,3-thiadiazoles under the influence of halogen-containing oxidizing to bis(triazolyl) disulfides was observed. Ammonia reduces the disulfides obtained to 5-mercapto-1,2,3-triazoles.

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References

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Authors and Affiliations

  1. Ural Polytechnical Institute, 620002, Ekaterinburg, Russia

    Yu. M. Shafran, V. A. Bakulev, V. A. Shevyrin & M. Yu. Kolobov

Authors
  1. Yu. M. Shafran
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  2. V. A. Bakulev
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  3. V. A. Shevyrin
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  4. M. Yu. Kolobov
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Additional information

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 6, pp. 840–846, June, 1993.

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Shafran, Y.M., Bakulev, V.A., Shevyrin, V.A. et al. Anomalous rearrangement of 1,2,3-thiadiazoles to 1,2,3-triazoles. Chem Heterocycl Compd 29, 724–729 (1993). https://doi.org/10.1007/BF00531556

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  • DOI: https://doi.org/10.1007/BF00531556

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