Abstract
The effect of small amounts (<5 mol %) of cobalt oxide on the electrical properties of cerium oxide solid solutions has been evaluated. Ce0.8Gd0.2O2-x (CGO) powder with an average crystallite size of 20 nm served as a model substance for the electrolyte material with a high oxygen ion conductivity and low electronic conductivity in its densified state. Doping the CGO powder by transition metal oxides (MeO) with concentrations below 2 mol % did not change the ionic conductivity nor the electrolytic domain boundary. After long sintering times (2 h) at temperatures above 900°C, MeO and CeO2 form solid solutions. However, short sintering times or high dopant concentrations lead to an electronic conducting grain boundary phase short circuiting the ionic conductivity of the CGO grains. Choosing proper doping levels, sintering time and temperature allows one to tailor mixed conducting oxides based on CGO. These materials have potential use as electrolytes and/or anodes in solid oxide fuel cells and ion separation membranes.
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References
N.Q. Minh, J. Am. Ceram. Soc., 76, 563 (1993).
S.A. Barnett, Energy, 15(1), 1 (1990).
T. Tsai and S.A. Barnett, J. Electrochem. Soc., 145(5), 1696 (1998).
C. Kleinlogel, M. Godickemeier, K. Honegger, and L.J. Gauckler, in Ionic and Mixed Conducting Ceramics III, edited by W.L. Worrell, et al., Pennington, NJ, The Electrochem. Soc. Inc., PV 97–24, 97 (1997).
T. Ishihara, H. Matsuda, and Y. Takita, J. Am. Chem. Soc., 116, 3801 (1994).
P. Shuk, H.-D. Wiemhofer, U. Guth, W. Gopel, and M. Greenblatt, Solid State Ionics, 89, 179 (1996).
M. Godickemeier and L.J. Gauckler, J. Electrochem. Soc., 145(2), 414 (1998).
T.H. Etsell and S.N. Flengas, Chem. Rev., 70, 339 (1970).
D. Schneider, M. Gödickemeier, and L.J. Gauckler, J. Electroceramics, 1:2, 165 (1997).
I. Riess, Solid State Ionics, 52, 127 (1992).
I. Riess, M. Gödickemeier, and L.J. Gauckler, Solid State Ionics, 90(1–4), 91 (1996).
E. Perry Murray, T. Tsai, and S.A. Barnett, Nature, 400, 649 (1999).
P.-L. Chen and I.-W. Chen, J. Am. Ceram. Soc., 76(6), 1577 (1993).
Y.C. Zhou and M.N. Rahaman, J. Am. Ceram. Soc., 78(4), 981 (1995).
J. Van Herle, T. Horita, T. Kawada, N. Sakai, H. Yokokawa, and M. Dokiya, Solid State Ionics, 86–88, 1255 (1996).
K. Eguchi, T. Setoguchi, T. Inoue, and H. Arai, Solid State Ionics, 52, 165 (1992).
P.-I. Chen and I.-W. Chen, J. Am. Ceram. Soc., 77(9), 2289 (1994).
J. Van Herle, T. Horita, T. Kawada, N. Sakai, H. Yokokawa, and M. Dokiya, J. Am. Ceram. Soc., 80(4), 933 (1997).
C. Kleinlogel and L.J. Gauckler, in Proceedings SSI-12, Solid State Ionics, (1999), accepted.
C. Kleinlogel and L.J. Gauckler, in Proceedings SOFC VI, Honolulu, Hawaii, (1999), accepted.
N.M. Beekmans and L. Heyne, Electrochimica. Acta, 21, 303 (1976).
T. Van Dijk and A.J. Burgraaf, Phys. Stat. Sol. (a), 63, 229 (1981).
J.E. Bauerl, J. Phys. Chem. Solids, 30, 2657 (1969).
J.-H. Hwang, D.S. McLachlan, and T.O. Mason, J. of Electroceramics, 3(1), 7 (1999).
N. Bonanos, B.C.H. Steele, and E.P. Butler, in Impedance Spectroscopy, edited by J.R. MacDonald (Wiley and Sons, New York, 1988), 191.
S.M. Haile, D.L. West, and J. Campbell, J. Mater. Res., 13(6), 1576 (1998).
G.M. Christie and F.P.F. Van berkel, Solid State Ionics, 83, 17 (1996).
A.K. Bose and D.P. Ray-Chaudhuri, Sci. and Culture, 3, 246 (1937).
M. Godickemeier, B. Heeb, B. Michel, K. Sasaki, P. Bolac, and L.J. Gauchler, J. of Materials Research, 9(5), 1228 (1994).
H. Nafe, Solid State Ionics, 13, 255 (1984).
T. Kawada, N. Sakai, H. Yokokawa, and M. Dokiya, Solid State Ionics, 53-56, 418 (1992).
S.S. Liou and W.L. Worrell, Appl. Phys., A49, 25 (1989).
E.J.L. Schouler and M. Kleitz, J. Electrochem. Soc., 134, 1045 (1987).
K.R. Thampi, A.J. McEvoy, and J. Van Herle, J. Electrochem. Soc., 142, 506 (1995).
B.C.H. Steele, Solid State Ionics, 75, 157 (1995).
P.S. Manning, J.D. Sirman, and J.A. Kilner, Solid State Ionics, in press.
K. Sasaki, P. Murugaraj, M. Haseidl, and J. Maier, in Solid Oxide Fuel Cells V, U. Stimming, S.C. Shingal, H. Tagawa, and W. Lehnert, eds, vol. 97–40, The Electrochem. Soc. Inc., Pennington, NJ, 1190 (1997).
H.L. Tuller, in Nonstoichiometrie in Oxides, edited by O.T. Sörensen, Academic Press, NY, 271 (1981).
R. Korner, M. Ricken, J. Nolting, and I. Riess, J. Solid State Chem., 78, 136 (1989).
M.A. Panhans and R.N. Blumenthal, Solid State Ionics, 60, 279 (1993).
M. Mogensen, T. Lindegaard, U.R. Hansen, and G. Mogensen, J. Electrochem. Soc., 141, 2122 (1994).
H.L. Tuller and A.S. Nowick, J. Electrochem. Soc., 126(2), 209 (1979).
M. Godickemeier, ETH Dissertation No. 11348, (1996).
The SGTE Substance Database version 1994, SGTE (Scientific Group Thermodata Europe), Grenoble, France, 1994.
T. Kudo and Y. Obayashi, J. Electrochem. Soc., 123, 415 (1976).
T. Kudo and H. Obayashi, J. Electrochem. Soc., 133(3), 415 (1976).
D.L. Maricle, T.E. Swarr, and S. Karavolis, Solid State Ionics, 52, 173 (1992).
A.I. Beljaev and J.E. Studencov, Legkie Metally, 6(3), 17 (1937).
G. Borchardt, K. Kowalski, J. Nowotny, M. Rekas, and W. Weppner, J. Eur. Cer. Soc., 14, 369 (1994).
C. Wagner and E. Koch, Z. phys. Chem. B, 32, 439 (1936).
R.T. Distine, R.N. Blumenthal, and T.F. Kuech, J. Electrochem. Soc., 126(2), 264 (1979).
H. Yahiro, K. Eguchi, and H. Arai, Solid State Ionics, 36, 71 (1989).
H. Yahiro, T. Ohuchi, K. Eguchi, and H. Arai, J. Mater. Sci., 23, 1036 (1988).
G. Dontsov, G. Vitter, and C. Déportes, Rev. Int. Hautes Tempér. et Réfract., 9, 147 (1972).
E.N. Naumovic, V.V. Kharton, A.V. Kovalevsky, and V.V. Samokhval, in Proc. of the 17th Riso International Symposium on Materials Science, edited by F.W. Poulsen, N. Bonanos, S. Lindevoth, H. Mogensen, B. Zachau-Christiansen, P375 Denmark (1996).
J.D. Sirman, D. Waller, and J.A. Kilner, in Proceedings of the Fith Inl. Symp. on Solida Oxide Fuel Cells, edited by U. Stimming, S.C. Singhl, H. Tagawa, W. Lehnert. The Electrochemical Society Inc., Pennington, NJ, PV 97–18, 1159 (1997).
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Kleinlogel, C., Gauckler*, L. Mixed Electronic-Ionic Conductivity of Cobalt Doped Cerium Gadolinium Oxide. Journal of Electroceramics 5, 231–243 (2000). https://doi.org/10.1023/A:1026583629995
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DOI: https://doi.org/10.1023/A:1026583629995