Abstract
Besides the known sarmentogenin 3-O-β-D-allopyranoside (1) and digitoxigenin-3-O-[β-D-xylopyranosyl-(1→4)-2′, 3′-di-O-acetyl-β-D-allopyranoside] (4), four new cardiac glycosides (2, 3, 5 and6) have been isolated from the defensive glands of adults ofChrysolina fuliginosa. The structures of the new compounds were determined by1H NMR at 600 MHz and FABMS. Compounds1–6, present in the adults ofC. fuliginosa, have also been identified in the eggs.
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Hilker, M., Daloze, D. & Pasteels, J.M. Cardenolide glycosides from the adults and eggs of Chrysolina fuliginosa (Coleoptera: Chrysomelidae). Experientia 48, 1023–1027 (1992). https://doi.org/10.1007/BF01919158
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DOI: https://doi.org/10.1007/BF01919158