Summary
The major components of the sex pheromone system ofPanolis flammea, pine beauty moth have been identified as (Z)-9-tetradecenyl acetate, (Z)-11-hexadecenyl acetate and (Z)-11-tetradecenyl acetate in the ratio 100∶5∶1; the double bond position of these derivatives was established by microscale application of a methoxymercuration-demercuration technique and GC-MS followed by multiple ion monitoring.
Similar content being viewed by others
References
J.T. Stoakley, Forestry Commission Forest Record No. 120, H.M.S.O., 1979.
J.M. Brand, J.C. Young and R.M. Silverstein, Fortschr. Chem. org. Natstoffe37, 1 (1979).
P. Abley, F.J. McQuillen, D.E. Minnikin, K. Kusamran, K. Maskens and N. Polgar, J. chem. Soc. chem. Commun.1970. 348.
5% OV101, 100°–300° at 6°/min; 5% OV17, 100°–325° at 6°/ min; Carbowax 20M SCOT capillary, 80°–200° at 4%/min.
E.C. Uebel, M. Schwartz, R.E. Menzer and R.W. Miller, J. chem. Ecol.4, 73 (1978).
G.J. Blomquist, R.W. Howard, C.A. McDaniel, S. Remaley, L.A. Dwyer and D.R. Nelson, J. chem. Ecol.6, 257 (1980).
5% OV101, 180°–300° at 4°/min; 5% OV17, 220°–325° at 6°/min; SE30 SCOT capillary 160°–300° at 4°/min.
E. Priesner, M. Jacobson and H.E. Bestmann, Z. Naturf.30c, 283 (1975).
E. Priesner, H. Bogenschultz, W. Altenkirch and H. Arn, Z. Naturf.33c, 1000 (1978).
Author information
Authors and Affiliations
Additional information
We thank the Science Research Council and Forestry Commission for financial support. We are grateful for the collaboration of Messrs Stoakley and Bevan, Dr C. Longhurst and Mrs J. Edwards.
Rights and permissions
About this article
Cite this article
Baker, R., Bradshaw, J.W.S. & Speed, W. Methoxymercuration-demercuration and mass spectrometry in the identification of the sex pheromones ofPanolis flammea, the pine beauty moth. Experientia 38, 233–234 (1982). https://doi.org/10.1007/BF01945083
Published:
Issue Date:
DOI: https://doi.org/10.1007/BF01945083