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Hybrid and biohybrid layered double hydroxides for electrochemical analysis

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Abstract

Layered double hydroxides (LDH) are lamellar materials that have been extensively used as electrode modifiers. Nanostructured organic–inorganic materials can be designed by intercalation of organic or metallic complexes within the interlayer space of these materials or by the formation of composite materials based on biopolymers (alginate or chitosan) or biomolecules, such as enzymes. These hybrid or biohybrid materials have interesting properties applicable in electroanalytical devices. From an exhaustive review of the literature, the relevance of these hybrid and biohybrid LDH materials as electrode materials for electrochemical detection of species with an environmental or health impact is evaluated. The analytical characteristics (sensitivity and detection limit) of LDH-based amperometric sensors or biosensors are scrutinized.

(Bio) Hybrid LDH based modified electrodes

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Abbreviations

ABTS:

2,2′-Azinobis(3-ethylbenzothiazoline-6-sulfonate)

AQS:

Anthraquinone sulfonate

CoPcTS:

Cobalt phthalocyanine tetrasulfonate

GOx:

Glucose oxidase

HCF:

Hexacyanoferrate

HRP:

Horseradish peroxidase

LbL:

Layer by layer

LDH:

Layered double hydroxide

LoD:

Limit of detection

NGB:

Naphthol green B

PPO:

Polyphenol oxidase

SDS:

Sodium dodecyl sulfate

TSPP:

meso-Tetrakis(p-sulfonatophenyl) porphyrin

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Authors and Affiliations

  1. Institut de Chimie de Clermont-Ferrand, Clermont Université, Université Blaise Pascal, BP 10448, 63000, Clermont-Ferrand, France

    Christine Mousty & Vanessa Prévot

  2. CNRS, UMR6296, ICCF, BP 80026, 63171, Aubière, France

    Christine Mousty & Vanessa Prévot

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  1. Christine Mousty
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  2. Vanessa Prévot
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Correspondence to Christine Mousty.

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Published in the topical collection Amperometric Sensing with guest editors Renato Seeber, Fabio Terzi, and Chiara Zanardi.

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Mousty, C., Prévot, V. Hybrid and biohybrid layered double hydroxides for electrochemical analysis. Anal Bioanal Chem 405, 3513–3523 (2013). https://doi.org/10.1007/s00216-013-6797-1

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