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Licensed Unlicensed Requires Authentication Published by De Gruyter January 23, 2020

Machiite, Al2Ti3O9, a new oxide mineral from the Murchison carbonaceous chondrite: A new ultra-refractory phase from the solar nebula

  • Alexander N. Krot EMAIL logo , Kazuhide Nagashima and George R. Rossman
From the journal American Mineralogist

Abstract

Machiite (IMA 2016-067), Al2Ti3O9, is a new mineral that occurs as a single euhedral crystal, 4.4 μm in size, in contact with an euhedral corundum grain, 12 μm in size, in a matrix of the Murchison CM2 carbonaceous chondrite. The mean chemical composition of holotype machiite by electron probe microanalysis is (wt%) TiO2 59.75, Al2O3 15.97, Sc2O3 10.29, ZrO2 9.18, Y2O3 2.86, FeO 1.09, CaO 0.44, SiO2 0.20, MgO 0.10, total 99.87, giving rise to an empirical formula (based on 9 oxygen atoms pfu) of (Al1.17Sc0.56Y0.10Ti0.084+Fe0.06Ca0.03Mg0.01)(Ti2.714+Zr0.28Si0.01)O9.The general formula is (Al,Sc)2(Ti4+,Zr)3O9. The end-member formula is Al2Ti3O9. Machiite has the C2/c schreyerite-type structure with a = 17.10 Å, b = 5.03 Å, c = 7.06 Å, b = 107°, V = 581 Å3, and Z = 4, as revealed by electron backscatter diffraction. The calculated density using the measured composition is 4.27 g/cm3. The machiite crystal is highly 16O-depleted relative to the coexisting corundum grain (ᐃ17O = –0.2 ± 2.4‰ and –24.1 ± 2.6‰, respectively; where ᐃ17O = δ17O– 0.52 × δ18O). Machiite is a new member of the schreyerite (V2Ti3O9) group and a new Sc,Zr-rich ultrarefractory phase formed in the solar nebula, either by gas-solid condensation or as a result of crystallization from a Ca,Al-rich melt having solar-like oxygen isotopic composition (ᐃ17O ~ –25‰) under high-temperature (~1400–1500 °C) and low-pressure (~10-4–10-5 bar) conditions in the CAI-forming region near the protosun. The currently observed disequilibrium oxygen isotopic composition between machiite and corundum may indicate that machiite subsequently experienced oxygen isotopic exchange with a planetary-like 16O-poor gaseous reservoir either in the solar nebula or on the CM chondrite parent body. The name machiite is in honor of Chi Ma, mineralogist at California Institute of Technology, for his contributions to meteorite mineralogy and discovery of many new minerals representing extreme conditions of formation.



Acknowledgments and Funding

Comments and suggestions by J. Han, O. Tschauner, and anonymous reviewer are highly appreciated. SEM, EBSD, and EPMA were carried out at the Geological and Planetary Science Division Analytical Facility, Caltech, which is supported in part by NSF grants EAR-0318518 and DMR-0080065. SIMS was carried out at University of Hawai‘i. Raman was carried out in the Rossman lab at Caltech. This work was also supported by NASA grant NNX17AE22G (P.I., A.N. Krot).

References cited

Armstrong, J.T. (1995) CITZAF: A package of correction programs for the quantitative electron beam X‑ray analysis of thick polished materials, thin films, and particles. Microbeam Analysis, 4, 177–200.Search in Google Scholar

Brearley, A.J., and Krot, A.N. (2012) Metasomatism in the early solar system: The record from chondritic meteorites. In D.E. Harlov and H. Austrheim, Eds., Metasomatism and the Chemical Transformation of Rock, Lecture Notes in Earth System Sciences, Springer, pp. 659–789.Search in Google Scholar

Clayton, R.N., Grossman, L., and Mayeda, T.K. (1973) A component of primitive nuclear composition in carbonaceous chondrites. Science, 182, 482–485.10.1126/science.182.4111.485Search in Google Scholar

Clayton, R.N., Onuma, N., Grossman, L., and Mayeda, T.K. (1977) Distribution of the presolar component in Allende and other carbonaceous chondrites. Earth and Planetary Science Letters, 34, 209–224.10.1016/0012-821X(77)90005-XSearch in Google Scholar

Colomban, P., and Mazerolles, L. (1991) Nanocomposites in mullite-ZrO2 and mellite-TiO2 systems synthesised through alkoxide hydrolysis gel routes: microstructure and fractography. Journal of Materials Science, 26, 3503–3510.10.1007/BF00557138Search in Google Scholar

Döbelin, N., Reznitsky, L.Z., Sklyarov, E.V., Armbruster, T., and Medenbach, O. (2006) Schreyerite, V2Ti3O9 New occurrence and crystal structure. American Mineralogist, 91, 196–202.10.2138/am.2006.1893Search in Google Scholar

Guo, W., and Eiler, J.M. (2007) Temperatures of aqueous alteration and evidence for methane generation on the parent bodies of the CM chondrites. Geochimica et Cosmochimica Acta, 71, 5565–5575.10.1016/j.gca.2007.07.029Search in Google Scholar

Komatsu, M., Fagan, T.J., Krot, A.N., Nagashima, K., Petaev, M.I., Kimura, M., and Yamaguchi, A. (2018) First evidence for silica condensation within the solar protoplanetary disk. Proceeding of National Academy of Sciences, 115, 7497–7502.10.1073/pnas.1722265115Search in Google Scholar PubMed PubMed Central

Kööp, L., Nakashima, D., Heck, P.R., Kita, N.T., Tenner, T.J., Krot, A.N., Nagashima, K., Park, C., and Davis, A.M. (2016) New constraints for the relationship between 26Al and oxygen, calcium, and titanium isotopic variation in the early Solar System from a multi-element isotopic study of Spinel-Hibonite Inclusions. Geochimica et Cosmochimica Acta, 184, 151–172.10.1016/j.gca.2016.04.018Search in Google Scholar

Krot, A.N. (2016) Machiite, IMA 2016-067. CNMNC Newsletter No. 34, December 2016, page 1317. Mineralogical Magazine, 80, 1315–1321.Search in Google Scholar

Krot, A.N., Nagashima, K., Van Kooten, E.M.M., and Bizzarro, M. (2017a) High-temperature rims around calcium-aluminum-rich inclusions from the CR, CB and CH carbonaceous chondrites. Geochimica et Cosmochimica Acta, 201, 155–184.10.1016/j.gca.2016.09.031Search in Google Scholar

Krot, A.N., Nagashima, K., Van Kooten, E.M.M., and Bizzarro, M. (2017b) Calcium-aluminum-rich inclusions recycled during formation of porphyritic chondrules from CH carbonaceous chondrites. Geochimica et Cosmochimica Acta, 201, 185–223.10.1016/j.gca.2016.09.001Search in Google Scholar

Krot, A.N., Ma, C., Nagashima, K., Davis, A.M., Beckett, J.R., Simon, S.B., Komatsu, M., Fagan, T.J., Brenker, F., Ivanova, M.A., and Bischoff, A. (2019) Mineralogy, petrography, and oxygen isotopic compositions of ultrarefractory inclusions from carbonaceous chondrites. Geochemistry, 79, 125519.10.1016/j.chemer.2019.07.001Search in Google Scholar

Lee, M.R., Cohen, B.E., and King, A.J. (2019) Alkali-halogen metasomatism of Meteorite Hills 01075 (CM2) driven by shock heating: An analogue for Ryugu. 82nd Annual Meeting of the Meteoritical Society, Abstract 6070.Search in Google Scholar

Lodders, K. (2003) Solar system abundances and condensation temperatures of the elements. Astrophysical Journal, 591, 1220–1247.10.1086/375492Search in Google Scholar

Ma, C., and Rossman, G.R. (2008) Barioperovskite, BaTiO3 a new mineral from the Benitoite Mine, California. American Mineralogist, 93, 154–157.10.2138/am.2008.2636Search in Google Scholar

Ma, C., and Rossman, G.R. (2009) Tistarite, Ti2O3 a new refractory mineral from the Allende meteorite. American Mineralogist, 94, 841–844.10.2138/am.2009.3203Search in Google Scholar

Ma, C., Beckett, J.R., and Rossman, G. (2014) Allendeite, (Sc4Zr4O12 and hexamolybdenum (Mo,Ru,Fe), two new minerals from an ultrarefractory inclusion from the Allende meteorite. American Mineralogist, 99, 654–666.10.2138/am.2014.4667Search in Google Scholar

Ma, C., Tschauner, O., Beckett, J.R., Liu, Y., Rossman, G.R., Zhuravlev, K., Prakapenka, V., Dera, P., and Taylor, L.A. (2015) Tissintite, (Ca,Na,□) AlSi2O6 a highly-defective, shock-induced, high-pressure clinopyroxene in the Tissint martian meteorite. Earth and Planetary Science Letters, 422, 194–205.10.1016/j.epsl.2015.03.057Search in Google Scholar

Ma, C., Tschauner, O., Becket, J.R., Liu, Y., Rossman, G.R., Sinogeikin, S.V., Smith, J.S., and Taylor, L.A. (2016) Ahrensite, γ-Fe2SiO4 a new shock-metamorphic mineral from the Tissint meteorite: implications for the Tissint shock event on Mars. Geochimica et Cosmochimica Acta, 184, 240–256.10.1016/j.gca.2016.04.042Search in Google Scholar

Makide, K., Nagashima, K., Krot, A.N., Huss, G.R., Hutcheon, I.D., and Bischoff, A. (2009) Oxygen- and magnesium-isotope compositions of calcium-aluminum-rich inclusions from CR2 carbonaceous chondrites. Geochimica et Cosmochimica Acta, 73, 5018–5051.10.1016/j.gca.2009.01.042Search in Google Scholar

Makide, K., Nagashima, K., Krot, A.N., Huss, G.R., Hutcheon, I.D., Hellebrand, E., and Petaev, M.I. (2013) Heterogeneous Distribution of 26Al at the Birth of the Solar System: Evidence from Corundum-bearing Refractory Inclusions in Carbonaceous Chondrites. Geochimica et Cosmochimica Acta, 110, 190–215.10.1016/j.gca.2013.01.028Search in Google Scholar

McKeegan, K.D., Kallio, A.P.A., Heber, V.S., Jarzebinski, G., Mao, P.H., Coath, C.D., Kunihiro, T., Wiens, R.C., Nordholt, J.E., Moses, R.W. Jr., and others. (2011) The oxygen isotopic composition of the Sun inferred from captured solar wind. Science, 332, 1528–1532.10.1126/science.1204636Search in Google Scholar PubMed

Pang, R.-L., Harries, D., Pollok, K., Zhang, A.-C., and Langenhorst, F. (2018) Vestaite, (Ti4+Fe2+a new mineral in the shocked eucrite Northwest Africa 8003. American Mineralogist, 103, 1502–1511.10.2138/am-2018-6522Search in Google Scholar

Tschauner, O., Ma, C., Beckett, J.R., Prescher, C., Prakapenka, V.B., and Rossman, G.R. (2014) Discovery of bridgmannite, the most abundant mineral in Earth, in a shocked meteorite. Science, 346, 1100–1102.10.1126/science.1259369Search in Google Scholar PubMed

Ushikubo, T., Kimura, M., Kita, N.T., and Valley, J.W. (2012) Primordial oxygen isotope reservoirs of the solar nebula recorded in chondrules in Acfer 094 carbonaceous chondrite. Geochimica et Cosmochimica Acta, 90, 242–264.10.1016/j.gca.2012.05.010Search in Google Scholar

Yurimoto, H., Ito, M., and Nagasawa, H. (1998) Oxygen isotope exchange between refractory inclusion in Allende and solar nebula gas. Science, 282, 1874–1877.10.1126/science.282.5395.1874Search in Google Scholar

Received: 2019-06-28
Accepted: 2019-09-25
Published Online: 2020-01-23
Published in Print: 2020-02-25

© 2020 Walter de Gruyter GmbH, Berlin/Boston

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