Nonadiabatic Low-Temperature Quantum Diffusion of Hydrogen in Nb(OH)x

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, , Citation D. Steinbinder et al 1988 EPL 6 535 DOI 10.1209/0295-5075/6/6/011

0295-5075/6/6/535

Abstract

The local jump diffusion of trapped H in two Nb(OH)x samples was investigated between 10 and 160 K by neutron spectroscopy. The jump rates vary by less than a factor of 7. Below ∼ 70 K, they exhibit Kondo's T2K-1 temperature power law for a diffusion process that is controlled by nonadiabatic coupling to conduction electrons. Above ∼ 70 K, the diffusion is dominated by the interaction with phonons.

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10.1209/0295-5075/6/6/011