Density matrix renormalization group studies of the effect of constraint release on the viscosity of polymer melts

Matthias Paeßens and Gunter M. Schütz
Phys. Rev. E 66, 021806 – Published 28 August 2002
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Abstract

The scaling of the viscosity of polymer melts is investigated with regard to the molecular weight. We present a generalization of the Rubinstein-Duke model, which takes constraint releases into account and calculates the effects on the viscosity by the use of the density matrix renormalization group algorithm. Using input from Rouse theory, the rates for the constraint releases are determined in a self-consistent way. We conclude that shape fluctuations of the tube caused by constraint release are not a likely candidate for improving Doi’s crossover theory for the scaling of the polymer viscosity.

  • Received 28 January 2002

DOI:https://doi.org/10.1103/PhysRevE.66.021806

©2002 American Physical Society

Authors & Affiliations

Matthias Paeßens* and Gunter M. Schütz

  • Institut für Festkörperforschung, Forschungszentrum Jülich-52425 Jülich, Germany

  • *Electronic address: m.paessens@fz-juelich.de

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Vol. 66, Iss. 2 — August 2002

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