Real-space characterization of short-range order in Cu-Pd alloys

M. Rodewald, K. Rodewald, P. De Meulenaere, and G. Van Tendeloo
Phys. Rev. B 55, 14173 – Published 1 June 1997
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Abstract

Cu-Pd alloys containing 10, 20, 30, 40, and 50 at. % Pd and quenched from a temperature just above the ordering temperature Tc are investigated by electron diffraction and high-resolution electron microscopy (HREM). The results show diffuse electron diffraction intensities at {100} and {110} positions for the alloy with 10 at. % Pd, but with a characteristic twofold and fourfold splitting for the alloys with more than 10 at. % Pd. High-resolution images show the formation of microdomains best developed between 20 and 30 at. % Pd. A real-space characterization has been performed by applying videographic real-structure simulations revealing that the splitting of the diffuse maxima depends on the average distance between microdomains of Cu3Au-type in antiphase with each other. By applying image processing routines on the HREM images, correlation vectors are identified which correspond to correlations between microdomains.

  • Received 28 October 1996

DOI:https://doi.org/10.1103/PhysRevB.55.14173

©1997 American Physical Society

Authors & Affiliations

M. Rodewald

  • TH Darmstadt, Fachbereich Materialwissenschaft, Fachgebiet Strukturforschung, Petersenstrasse 23, D-64287 Darmstadt, Germany

K. Rodewald

  • Universität Hannover, Institut für Mineralogie, Welfengarten 1, D-30167 Hannover, Germany

P. De Meulenaere and G. Van Tendeloo

  • EMAT, Universiteit Antwerpen (RUCA), Groenenborgerlaan 171, B-2020 Antwerpen, Belgium

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Vol. 55, Iss. 21 — 1 June 1997

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