Skip to main content
SpringerLink
Log in

Layers of cyclam-substituted PVC with sodium hydroxide aqua complexes with aza-crown ligands on cellulose tissue filled with active coal

  • Physical Chemistry of Surface Phenomena
  • Published:
Russian Journal of Physical Chemistry A Aims and scope Submit manuscript

Abstract

A material with an electrically ОН–-conductive porous layer of cyclam-substituted PVC filled with active coal containing NaOH aqua complexes with aza-crown ligands and cross-linked with the surface of cellulose tissue fibers has been synthesized. The structure of the material was studied. Its sorption capacity in vapors and liquid benzene and hexane, specific resistance, potential of ОН- transfer from solution to layer, and rate constants of ОН– travel in the layer of the material as an electrochemical bridge in vapors and liquid benzene and hexane were determined. The aqua complexes decomposed in the layer with formation of Н2 during the cathodic polarization of the bridge and О2 during the anodic polarization; the composition of the complexes was regenerated due to the motion of ОН–.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. A. Ya. Fridman, A. Yu. Tsivadze, E. M. Morozova, N. P. Sokolova, A. M. Voloshchuk, G. A. Petukhova, I. I. Bardyshev, A. M. Gorbunov, A. K. Novikov, I. Ya. Polyakova, V. N. Titova, A. A. Yavich, N. V. Petrova, and O. K. Krasil’nikova, Russ. J. Phys. Chem. A 89, 1305 (2015).

    Article  Google Scholar 

  2. A. Yu. Tsivadze, A. Ya. Fridman, A. M. Morozova, N. P. Sokolova, A. M. Voloshchuk, G. A. Petukhova, I. I. Bardyshev, A. K. Novikov, A. M. Gorbunov, I.Ya.Polyakova, V. N. Titova, A. A. Yavich, and N. V. Petrova, Russ. J. Phys. Chem. A 89, 265 (2015).

    Article  CAS  Google Scholar 

  3. A. L. Volynskii and N. F. Bakeev, Structural Self-organization of Amorphous Polymers (Fizmatlit, Moscow, 2005) [in Russian].

    Google Scholar 

  4. A. Yu. Tsivadze, A. Ya. Fridman, A. M. Voloshchuk, E. M. Morozova, N. P. Sokolova, I. I. Bardyshev, A. M. Gorbunov, G. A. Petukhova, I. Ya. Polyakova, and O. P. Shapokhina, Prot. Met. Phys. Chem. Surf. 49, 554 (2013).

    Article  CAS  Google Scholar 

  5. P. G. Painter, M. M. Coleman, and J. L. Koenig, The Theory of Vibrational Spectroscopy and Its Application to Polymeric Materials (Wiley, New York, 1986).

    Google Scholar 

  6. Infrared Spectroscopy of Polymers, Ed. by I. Dechant (Khimiya, Moscow, 1972; Akademic, Berlin, 1972).

  7. G. A. Petukhova, Ross. Khim. Zh. 39, 7 (1995).

    Google Scholar 

  8. A. M. Voloshchuk, M. M. Dubinin, T. A. Moskovskaya, G. K. Ivakhnyuk, and N. F. Fedorov, Russ. Chem. Bull. 37, 204 (1988).

    Article  Google Scholar 

  9. K. Nakamoto, Infrared and Raman Spectra of Inorganic and Coordination Compounds (Wiley, New York, 2009).

    Google Scholar 

  10. G. A. Krestov, A. Ya. Fridman, V. V. Myasoedova, et al., Non-aqueous Solutions in Engineering and Technology (Nauka, Moscow, 1991) [in Russian].

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Moscow, Russia

    A. Ya. Fridman, A. Yu. Tsivadze, E. M. Morozova, N. P. Sokolova, A. M. Voloshchuk, G. A. Petukhova, I. I. Bardyshev, A. M. Gorbunov, A. K. Novikov, I. Ya. Polyakova, V. N. Titova, A. A. Yavich & N. V. Petrova

Authors
  1. A. Ya. Fridman
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. Yu. Tsivadze
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. E. M. Morozova
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. N. P. Sokolova
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. A. M. Voloshchuk
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. G. A. Petukhova
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. I. I. Bardyshev
    View author publications

    You can also search for this author in PubMed Google Scholar

  8. A. M. Gorbunov
    View author publications

    You can also search for this author in PubMed Google Scholar

  9. A. K. Novikov
    View author publications

    You can also search for this author in PubMed Google Scholar

  10. I. Ya. Polyakova
    View author publications

    You can also search for this author in PubMed Google Scholar

  11. V. N. Titova
    View author publications

    You can also search for this author in PubMed Google Scholar

  12. A. A. Yavich
    View author publications

    You can also search for this author in PubMed Google Scholar

  13. N. V. Petrova
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to I. I. Bardyshev.

Additional information

Original Russian Text © A.Ya. Fridman, A.Yu. Tsivadze, E.M. Morozova, N.P. Sokolova, A.M. Voloshchuk, G.A. Petukhova, I.I. Bardyshev, A.M. Gorbunov, A.K. Novikov, I.Ya. Polyakova, V.N. Titova, A.A. Yavich, N.V. Petrova, 2016, published in Zhurnal Fizicheskoi Khimii, 2016, Vol. 90, No. 3, pp. 418–424.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Fridman, A.Y., Tsivadze, A.Y., Morozova, E.M. et al. Layers of cyclam-substituted PVC with sodium hydroxide aqua complexes with aza-crown ligands on cellulose tissue filled with active coal. Russ. J. Phys. Chem. 90, 641–646 (2016). https://doi.org/10.1134/S0036024416030109

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0036024416030109

Keywords

Search

Navigation