Abstract
The dependence of the physicomechanical properties of epoxy nanocomposites subjected to heat and humidity aging on the type of covalently functionalized carbon nanotubes and on the uniformity of their distribution in the epoxy matrix was studied. Two types of carbon nanotubes were used: those modified with carboxy and amide groups. The elastic modulus, bending deflection, and ultimate bending strength for the initial epoxy nanocomposites with carbon nanotubes and for those subjected to heat and humidity aging were determined. The epoxy binders modified with carboxylated carbon nanotubes are more resistant to the action of aging factors. The presence of aggregates of carboxylated carbon nanotubes in the epoxy matrix positively influences the preservation of physicomechanical properties of the composite subjected to heat and humidity aging. Microscopic examination revealed structural features of the epoxy nanocomposite and their effect on the resistance of the composite to the heat and humidity aging.
Similar content being viewed by others
References
Rakov, E.G., Russ. Chem. Rev., 2013, vol. 82, no. 1, pp. 27–47.
Kablov, E.N., Aviats. Mater. Tekhnol., 2015, no. 1 (34), pp. 3–33.
Kablov, E.N., Kondrashov, S.V., and Yurkov, G.Yu., Ross. Nanotekhnol., 2013, vol. 8, nos. 3–4, pp. 28–42.
Irzhak, V.I., Russ. Chem. Rev., 2011, vol. 80, no. 8, pp. 787–806.
Fan-Long, J. and Soo-Jin, P., Carbon Lett., 2011, vol. 12, no. 2, pp. 57–69.
Bauhofer, W. and Kovacs, J.Z., Composites Sci. Technol., 2009, vol. 69, pp. 1486–1498.
Grossiord, N., Loos, J., van Laake, L., et al., Adv. Funct. Mater., 2008, vol. 18, pp. 3226–3234.
Polymer–Carbon Nanotube Composites. Preparation, Properties and Applications, McNally, T. and Potschke, P., Eds., Woodhead, 2011, p. 805.
Lubineau, G. and Rahaman, A., Carbon, 2012, vol. 50, pp. 2377–2395.
Prusty, R.K., Rathore, D.K., Shukia, M.J., and Ray, B.Ch., Composites, Part B: Engineering, 2015, vol. 83, pp. 166–174.
Guadagno, L., De Vivo, B., Di Bartolomeo, A., et al., Carbon, 2011, vol. 49, pp. 1919–1930.
Starkova, O., Buschhorn, S.T., Mannov, E., et al., Eur. Polym. J., 2013, vol. 49, no. 8, pp. 2138–2148.
Marakhovskii, P.S., Kondrashov, S.V., D’yachkova, T.P., et al., Perspekt. Mater., 2015, no. 6, pp. 48–56.
Bol’shakov, V.A., Kondrashov, S.V., Merkulova, Yu.I., et al., Aviats. Mater. Tekhnol., 2015, no. 2 (35), pp. 61–66.
Filistovich, D.V., Startsev, O.V., and Suranov, A.Ya., Prib. Tekh. Eksp., 2003, no. 4, pp. 163–164.
Ma, P.-Ch., Siddiqui, N.A., Marom, G., and Kim, J.-K., Composites, Part A, 2010, vol. 41, pp. 1345–1367.
Makhon’kov, A.Yu. and Startsev, O.V., Materialovedenie, 2013, no. 7, pp. 47–52.
D’yachkova, T.P. and Druzhinina, V.N., Sovrem. Probl. Nauki Obraz.: Elektronn. Zh., 2014, no. 6, URL: http://www.science-education.ru/120-15853 (addressed July 5, 2016).
Startsev, O.V., Aging of aviation polymer materials in a warm humid climate, Doctoral Dissertation (in the form of scientific report), Moscow: All-Union Inst. of Aviation Materials, 1990.
Perepechko, I.I., Akusticheskie metody issledovaniya polimerov (Acoustic Methods for Studying Polymers), Moscow: Khimiya, 1973.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © S.V. Kondrashov, Yu.I. Merkulova, P.S. Marakhovskii, T.P. D’yachkova, K.A. Shashkeev, O.V. Popkov, O.V. Startsev, M.V. Molokov, E.V. Kurshev, G.Yu. Yurkov, 2017, published in Zhurnal Prikladnoi Khimii, 2017, Vol. 90, No. 5, pp. 657−665.
Rights and permissions
About this article
Cite this article
Kondrashov, S.V., Merkulova, Y.I., Marakhovskii, P.S. et al. Degradation of physicomechanical properties of epoxy nanocomposites with carbon nanotubes upon heat and humidity aging. Russ J Appl Chem 90, 788–796 (2017). https://doi.org/10.1134/S1070427217050202
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1070427217050202