Skip to main content
SpringerLink
Log in

Analysis of the 300 and 600 MHz1H-NMR spectra of poly(3-vinyl thiopene)

  • Published:
Polymer Bulletin Aims and scope Submit manuscript

Summary

The 300 and 600 MHz1H-NMR spectra of poly-(3-vinyl thiophene) synthesized via free radical initiated polymerization are presented and analyzed. The spectra are similar to those of poly-(2-vinyl thiophene) and were interpreted in a like manner. The polymer was found to be atactic with a Pm value of 0.48±.05.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. H. Sato, Y. Tanaka and K. Hatada, J. Polym. Sci., Polym. Phys. Ed.,21 1667 (1983).

    Google Scholar 

  2. H. Sato and Y. Tanaka, ACS Symposium Series,247, 181 (1984).

    Google Scholar 

  3. H. J. Harwood, T. K. Chen and F. T. Lin, ACS Symposium Series,247, 197 (1984).

    Google Scholar 

  4. L. Shepherd, T. K. Chen and H. J. Harwood, Polym. Bull., 1, 445 (1979).

    Google Scholar 

  5. T. K. Chen, T. A. Gerkin and H. J. Harwood, Polymer Bull.,2, 34 (1980).

    Google Scholar 

  6. H. J. Harwood, T. K. Chen, A. DasGupta, J. F. Kinstle, E. R. Santee, L. Shepherd and F. T. Lin, ACS Polym. Prep.,26(1) 39 (1985).

    Google Scholar 

  7. S. J. Tsai, E. R. Santee and H. J. Harwood, ACS Polym. Prep,31(2), 472 (1990).

    Google Scholar 

  8. T. Kawamura, T. Uryu and K. Matsuzaki, Makromol. Chem. Rapid Commun.,3, 66 (1982).

    Google Scholar 

  9. A. E. Tonelli, Macromolecules,12, 252 (1979);16, 604 (1983).

    Google Scholar 

  10. D. L. Trumbo, T. Suzuki and H. J. Harwood, Polymer Bull.,4, 677 (1981).

    Google Scholar 

  11. D. L. Trumbo, T. Suzuki and H. J. Harwood, ACS Polym. Prep.,24(2) 360 (1983).

    Google Scholar 

  12. D. L. Trumbo, S. C. Guhaniyogi and H. J. Harwood, J. Polym. Sci., Polym. Phys. Ed.,26, 1331 (1988).

    Google Scholar 

  13. D. L. Trumbo, T. Suzuki and H. J. Harwood, ACS Polym. Prep.,24(2), 367 (1983).

    Google Scholar 

  14. A. Dworak, W. J. Freeman and H. J. Harwood, Polym. J.,17, 351 (1985).

    Google Scholar 

  15. D. L. Trumbo and H. J. Harwood, Polym. Bull..,18, 27 (1987).

    Google Scholar 

  16. D. L. Trumbo, T. K. Chen and H. J. Harwood, Macromolecules,14, 1138 (1981).

    Google Scholar 

  17. S. Rajagopalan and P. V.A. Ramen, Org., Syn., Coll. Vol.3, 425 (1955).

    Google Scholar 

  18. C. R. Adams, U. S. Pat 3,309,381 (1967).

  19. Y. Hachikara and M. Imoto, J. Soc. Chem. Ind. Jap.,45, 1908 (1942).

    Google Scholar 

  20. E. vonMeerwall, Comp. Phys. Comm.,11, 211 (1976).

    Google Scholar 

Download references

Author information

Author notes

  1. D. L. Trumbo

    Present address: The Glidden Company, 16651 Sprague Road, 44137, Strongsville, OH, USA

Authors and Affiliations

  1. Department of Polymer Science, University of Akron, 44325-3909, Akron, OH, USA

    D. L. Trumbo, F. T. Lin, F. M. Lin & H. J. Harwood

  2. Institute of Polymer Science, University of Akron, 44325-3909, Akron, OH, USA

    D. L. Trumbo, F. T. Lin, F. M. Lin & H. J. Harwood

  3. Department of Chemistry, University of Pittsburgh, 15261, Pittsburgh, PA, USA

    D. L. Trumbo, F. T. Lin, F. M. Lin & H. J. Harwood

Authors
  1. D. L. Trumbo
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. F. T. Lin
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. F. M. Lin
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. H. J. Harwood
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Trumbo, D.L., Lin, F.T., Lin, F.M. et al. Analysis of the 300 and 600 MHz1H-NMR spectra of poly(3-vinyl thiopene). Polymer Bulletin 28, 87–94 (1992). https://doi.org/10.1007/BF01045643

Download citation

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01045643

Keywords

Search

Navigation